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Main Title: Catalytic hydrogenation of α,β-unsaturated carboxylic acid derivatives using copper(i)/N-heterocyclic carbene complexes
Author(s): Zimmermann, Birte M.
Kobosil, Sarah C. K.
Teichert, Johannes F.
Type: Article
Language Code: en
Abstract: A simple and air-stable copper(I)/N-heterocyclic carbene complex enables the catalytic hydrogenation of enoates and enamides, hitherto unreactive substrates employing homogeneous copper catalysis and H2 as a terminal reducing agent. This atom economic transformation replaces commonly employed hydrosilanes and can also be carried out in an asymmetric fashion.
Issue Date: 28-Jan-2019
Date Available: 30-Apr-2019
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Sponsor/Funder: TU Berlin, Open-Access-Mittel - 2019
Journal Title: Chemical Communications
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 55
Issue: 16
Publisher DOI: 10.1039/C8CC09853K
Page Start: 2293
Page End: 2296
EISSN: 1364-548X
ISSN: 1359-7345
Appears in Collections:FG Organische Chemie / Nachhaltige Synthesechemie » Publications

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