Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-8719
Main Title: The Stability Challenges of Oxygen Evolving Catalysts: Towards a Common Fundamental Understanding and Mitigation of Catalyst Degradation
Author(s): Spöri, Camillo Wolfgang
Kwan, Jason Tai Hong
Bonakdarpour, Arman
Wilkinson, David P.
Strasser, Peter
Type: Article
Is Part Of: 10.14279/depositonce-8601
Language Code: en
Abstract: This review addresses the technical challenges, their scientific basis, as well as recent progress and the road ahead with respect to the stability and degradation of OER catalysts operating at electrolyzer anodes in acidic environments with an emphasis on MEA based operation. First, we start clarifying the complexity associated with the term “catalyst stability”, cover today’s performance targets and outline major catalyst degradation mechanisms and their mitigation strategies. Then we evaluate suitable in-situ experimental methods to get insight into catalyst degradation and describe achievements in tuning OER catalyst stability. Finally, we highlight the importance of identifying universal figures of merit for stability and develop a comprehensive accelerated life test (ALT) that would yield comparable performance data across labs and catalyst types. As a whole, this review will help to disseminate and highlight the important relations between structure, composition and stability of OER catalysis under different operating conditions.
URI: https://depositonce.tu-berlin.de/handle/11303/9676
http://dx.doi.org/10.14279/depositonce-8719
Issue Date: 4-May-2017
Date Available: 19-Aug-2019
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): accelerated lifetime tests
iridium
membranes
oxygen evolution reaction
water splitting
Sponsor/Funder: DFG, 221428535, Nanostructured mixed metal oxides for the electrocatalytic oxidation of water
DFG, 198634447, SPP 1613: Regenerativ erzeugte Brennstoffe durch lichtgetriebene Wasserspaltung: Aufklärung der Elementarprozesse und Umsetzungsperspektiven auf technologische Konzepte
License: http://rightsstatements.org/vocab/InC/1.0/
Journal Title: Angewandte Chemie International Edition
Publisher: Wiley-VCH
Publisher Place: Weinheim
Volume: 56
Issue: 22
Publisher DOI: 10.1002/anie.201608601
Page Start: 5994
Page End: 6021
EISSN: 1521-3773
ISSN: 1433-7851
Notes: Manuscript submitted unter different title: "The Stability Challenges of Oxygen Evolving Electrocatalysts: Towards a Common Fundamental Understanding and Mitigation of Catalyst Degradation"
Appears in Collections:FG Technische Chemie » Publications

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