Synthesis and vibrational spectroscopy of Fe-57-labeled models of [NiFe] hydrogenase: first direct observation of a nickel-iron interaction
| dc.contributor.author | Schilter, David | |
| dc.contributor.author | Pelmenschikov, Vladimir | |
| dc.contributor.author | Wang, Hongxin | |
| dc.contributor.author | Meier, Florian | |
| dc.contributor.author | Gee, Leland B. | |
| dc.contributor.author | Yoda, Yoshitaka | |
| dc.contributor.author | Kaupp, Martin | |
| dc.contributor.author | Rauchfuss, Thomas B. | |
| dc.contributor.author | Cramer, Stephen P. | |
| dc.date.accessioned | 2016-06-21T08:29:16Z | |
| dc.date.available | 2016-06-21T08:29:16Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | A new route to iron carbonyls has enabled synthesis of 57Fe-labeled [NiFe] hydrogenase mimic (OC)357Fe(pdt)Ni(dppe) (pdt = 1,3-propanedithiolate). Its study by nuclear resonance vibrational spectroscopy revealed Ni-57Fe vibrations, as confirmed by calcns. The modes are absent for [(OC)357Fe(pdt)Ni(dppe)]+, which lacks Ni-57Fe bonding, underscoring the utility of the analyses in identifying metal-metal interactions. | en |
| dc.identifier.eissn | 1364-548X | |
| dc.identifier.issn | 1359-7345 | |
| dc.identifier.pmid | 25237680 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/5560 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-5189 | |
| dc.language.iso | en | |
| dc.rights.uri | https://creativecommons.org/licenses/by/3.0/ | |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.title | Synthesis and vibrational spectroscopy of Fe-57-labeled models of [NiFe] hydrogenase: first direct observation of a nickel-iron interaction | en |
| dc.type | Article | en |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1039/c4cc04572f | |
| dcterms.bibliographicCitation.issue | 88 | |
| dcterms.bibliographicCitation.journaltitle | Chemical communications | en |
| dcterms.bibliographicCitation.originalpublishername | Royal Society of Chemistry | de |
| dcterms.bibliographicCitation.originalpublisherplace | Cambridge | de |
| dcterms.bibliographicCitation.pageend | 13472 | |
| dcterms.bibliographicCitation.pagestart | 13469 | |
| dcterms.bibliographicCitation.volume | 50 | |
| tub.accessrights.dnb | free | |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin |
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