Second Law and Non-Equilibrium Entropy of Schottky Systems—Doubts and Verification−

dc.contributor.authorMuschik, Wolfgang
dc.date.accessioned2019-08-07T14:48:14Z
dc.date.available2019-08-07T14:48:14Z
dc.date.issued2018-09-28
dc.date.updated2019-08-01T16:51:08Z
dc.description.abstractMeixner’s historical remark in 1969 “... it can be shown that the concept of entropy in the absence of equilibrium is in fact not only questionable but that it cannot even be defined....” is investigated from today’s insight. Several statements—such as the three laws of phenomenological thermodynamics, the embedding theorem and the adiabatical uniqueness—are used to get rid of non-equilibrium entropy as a primitive concept. In this framework, Clausius inequality of open systems can be derived by use of the defining inequalities which establish the non-equilibrium quantities contact temperature and non-equilibrium molar entropy which allow to describe the interaction between the Schottky system and its controlling equilibrium environment.en
dc.identifier.eissn1099-4300
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/9720
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-8758
dc.language.isoenen
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/en
dc.subject.ddc530 Physikde
dc.subject.othernon-equilibrium entropyen
dc.subject.otherschottky systemsen
dc.subject.otherinert partitionen
dc.subject.othersecond lawen
dc.subject.othercontact temperatureen
dc.subject.otherentropy-free thermodynamicsen
dc.subject.otherdefining inequalitiesen
dc.subject.otheradiabatical uniquenessen
dc.subject.otherclausius inequality of open systemsen
dc.titleSecond Law and Non-Equilibrium Entropy of Schottky Systems—Doubts and Verification−en
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.articlenumber740en
dcterms.bibliographicCitation.doi10.3390/e20100740en
dcterms.bibliographicCitation.issue10en
dcterms.bibliographicCitation.journaltitleEntropyen
dcterms.bibliographicCitation.originalpublishernameMDPIen
dcterms.bibliographicCitation.originalpublisherplaceBaselen
dcterms.bibliographicCitation.volume20en
tub.accessrights.dnbfreeen
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Theoretische Physikde
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.instituteInst. Theoretische Physikde
tub.publisher.universityorinstitutionTechnische Universität Berlinen

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