Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes

dc.contributor.authorKeess, Sebastian
dc.contributor.authorOestreich, Martin
dc.date.accessioned2018-04-19T08:48:01Z
dc.date.available2018-04-19T08:48:01Z
dc.date.issued2017
dc.description.abstractSafe- and convenient-to-handle surrogates of hazardous chemicals are always in demand. Recently introduced cyclohexa-1,4-dienes with adequate substitution fulfil this role as El+/H− equivalents in B(C6F5)3-catalysed transfer reactions of El–H to π- and σ-donors (C[double bond, length as m-dash]C/C[triple bond, length as m-dash]C and C[double bond, length as m-dash]O/C[double bond, length as m-dash]N). Surrogates of Si–H/Ge–H, H–H and even C–H bonds have been designed and successfully applied to ionic transfer hydrosilylation/hydrogermylation, hydrogenation and hydro-tert-butylation, respectively. These processes and their basic principles are summarised in this Minireview. The similarities and differences between these transfer reactions as well as the challenges associated with these transformations are discussed.en
dc.description.sponsorshipDFG, EXC 314, Unifying Concepts in Catalysisen
dc.description.sponsorshipDFG, Oe 249/11-1, 3-Silylierte Cyclohexa-1,4-diene als Surrogate für gasförmige und gesundheitsschädliche Hydrosilane in der Lewis-Säure-Katalyseen
dc.identifier.eissn2041-6539
dc.identifier.issn2041-6520
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/7647
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-6837
dc.language.isoen
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/
dc.subject.ddc540 Chemie und zugeordnete Wissenschaften
dc.titleCyclohexa-1,4-dienes in transition-metal-free ionic transfer processesen
dc.typeArticle
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/c7sc01657c
dcterms.bibliographicCitation.issue7
dcterms.bibliographicCitation.journaltitleChemical Scienceen
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistry (RSC)
dcterms.bibliographicCitation.originalpublisherplaceCambridge
dcterms.bibliographicCitation.pageend4695
dcterms.bibliographicCitation.pagestart4688
dcterms.bibliographicCitation.volume8
tub.accessrights.dnbfree
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Organische Chemie / Synthese und Katalysede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Organische Chemie / Synthese und Katalysede
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinde
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