An Isolable Bis(Silanone–Borane) Adduct

dc.contributor.authorLuecke, Marcel‐Philip
dc.contributor.authorPens, Elron
dc.contributor.authorYao, Shenglai
dc.contributor.authorDriess, Matthias
dc.date.accessioned2020-11-16T08:58:35Z
dc.date.available2020-11-16T08:58:35Z
dc.date.issued2020-03-11
dc.date.updated2020-11-02T16:07:16Z
dc.description.abstractThe reaction of bis(silylenyl)‐substituted ferrocene 1 with two molar equivalents of BPh3 yields the corresponding bis(silylene–borane) Lewis adduct 2. The latter is capable to activate CO2 to furnish the borane‐stabilized bis(silanone) 3 through mono‐oxygenation of the dative SiII→B silicon centers under release of CO. Removal of BPh3 from 3 with PMe3 affords the corresponding 1,3,2,4‐cyclodisiloxane and the Me3P−BPh3 adduct. All isolated new compounds were characterized and their molecular structures were determined by single‐crystal X‐ray diffraction analyses.en
dc.description.sponsorshipDFG, 390540038, EXC 2008: Unifying Systems in Catalysis "UniSysCat"en
dc.description.sponsorshipTU Berlin, Open-Access-Mittel – 2020en
dc.identifier.eissn1521-3765
dc.identifier.issn0947-6539
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/11953
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-10839
dc.language.isoenen
dc.rightsThis is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
dc.rights
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.otherFLP-chemistryen
dc.subject.othersilanonesen
dc.subject.othersilyleneen
dc.subject.othersmall-molecule activationen
dc.titleAn Isolable Bis(Silanone–Borane) Adducten
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1002/chem.202000235en
dcterms.bibliographicCitation.issue20en
dcterms.bibliographicCitation.journaltitleChemistry – A European Journalen
dcterms.bibliographicCitation.originalpublishernameWileyen
dcterms.bibliographicCitation.originalpublisherplaceNew York, NYen
dcterms.bibliographicCitation.pageend4504en
dcterms.bibliographicCitation.pagestart4500en
dcterms.bibliographicCitation.volume26en
tub.accessrights.dnbfreeen
tub.affiliationFak. 2 Mathematik und Naturwissenschaften>Inst. Chemie>FG Metallorganische Chemie und Anorganische Materialiende
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Metallorganische Chemie und Anorganische Materialiende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinen
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