An Isolable Bis(Silanone–Borane) Adduct
| dc.contributor.author | Luecke, Marcel‐Philip | |
| dc.contributor.author | Pens, Elron | |
| dc.contributor.author | Yao, Shenglai | |
| dc.contributor.author | Driess, Matthias | |
| dc.date.accessioned | 2020-11-16T08:58:35Z | |
| dc.date.available | 2020-11-16T08:58:35Z | |
| dc.date.issued | 2020-03-11 | |
| dc.date.updated | 2020-11-02T16:07:16Z | |
| dc.description.abstract | The reaction of bis(silylenyl)‐substituted ferrocene 1 with two molar equivalents of BPh3 yields the corresponding bis(silylene–borane) Lewis adduct 2. The latter is capable to activate CO2 to furnish the borane‐stabilized bis(silanone) 3 through mono‐oxygenation of the dative SiII→B silicon centers under release of CO. Removal of BPh3 from 3 with PMe3 affords the corresponding 1,3,2,4‐cyclodisiloxane and the Me3P−BPh3 adduct. All isolated new compounds were characterized and their molecular structures were determined by single‐crystal X‐ray diffraction analyses. | en |
| dc.description.sponsorship | DFG, 390540038, EXC 2008: Unifying Systems in Catalysis "UniSysCat" | en |
| dc.description.sponsorship | TU Berlin, Open-Access-Mittel – 2020 | en |
| dc.identifier.eissn | 1521-3765 | |
| dc.identifier.issn | 0947-6539 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/11953 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-10839 | |
| dc.language.iso | en | en |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | en |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.subject.other | FLP-chemistry | en |
| dc.subject.other | silanones | en |
| dc.subject.other | silylene | en |
| dc.subject.other | small-molecule activation | en |
| dc.title | An Isolable Bis(Silanone–Borane) Adduct | en |
| dc.type | Article | en |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1002/chem.202000235 | en |
| dcterms.bibliographicCitation.issue | 20 | en |
| dcterms.bibliographicCitation.journaltitle | Chemistry – A European Journal | en |
| dcterms.bibliographicCitation.originalpublishername | Wiley | en |
| dcterms.bibliographicCitation.originalpublisherplace | New York, NY | en |
| dcterms.bibliographicCitation.pageend | 4504 | en |
| dcterms.bibliographicCitation.pagestart | 4500 | en |
| dcterms.bibliographicCitation.volume | 26 | en |
| tub.accessrights.dnb | free | en |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Metallorganische Chemie und Anorganische Materialien | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.group | FG Metallorganische Chemie und Anorganische Materialien | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin | en |