Ionic Liquids as Surfactants in Aqueous Multiphase Systems for the Pd‐Catalyzed Hydrocarboxylation

dc.contributor.authorWeber, Ariane
dc.contributor.authorIsbrücker, Philipp
dc.contributor.authorSchmidt, Marcel
dc.contributor.authorSchomäcker, Reinhard
dc.date.accessioned2023-08-02T11:58:41Z
dc.date.available2023-08-02T11:58:41Z
dc.date.issued2020-12-11
dc.description.abstractThe suitability of ionic liquids (alkylmethylimidazolium bromides) as surfactants in an aqueous multiphase system for the Pd-catalyzed hydrocarboxylation of 1-dodecene is discussed. Attention is paid to the influence of these ionic liquids on the reaction performance and the phase separation. All tested ionic liquids are suitable as surfactants, but their concentration has a strong impact on the reaction performance. The resulting product concentrations are crucial for the phase behavior and so for the phase separation. In recycling experiments, the Pd-catalyst is successfully separated and reused.en
dc.description.sponsorshipDFG, 56091768, TRR 63: Integrierte chemische Prozesse in flüssigen Mehrphasensystemen
dc.description.sponsorshipTU Berlin, Open-Access-Mittel – 2020
dc.identifier.eissn1522-2640
dc.identifier.issn0009-286X
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/19707
dc.identifier.urihttps://doi.org/10.14279/depositonce-18506
dc.language.isoen
dc.relation.ispartof10.14279/depositonce-17886
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subject.ddc500 Naturwissenschaften und Mathematik::540 Chemie::542 Techniken, Ausstattung, Materialien
dc.subject.othercatalyst recyclingen
dc.subject.otherhomogeneous catalysisen
dc.subject.otherionic liquidsen
dc.subject.othermultiphase systemsen
dc.titleIonic Liquids as Surfactants in Aqueous Multiphase Systems for the Pd‐Catalyzed Hydrocarboxylation
dc.typeArticle
dc.type.versionpublishedVersion
dcterms.bibliographicCitation.doi10.1002/cite.202000165
dcterms.bibliographicCitation.issue1-2
dcterms.bibliographicCitation.journaltitleChemie Ingenieur Technik
dcterms.bibliographicCitation.originalpublishernameWiley
dcterms.bibliographicCitation.originalpublisherplaceNew York, NY
dcterms.bibliographicCitation.pageend207
dcterms.bibliographicCitation.pagestart201
dcterms.bibliographicCitation.volume93
dcterms.rightsHolder.referenceCreative-Commons-Lizenz
tub.accessrights.dnbfree
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Technische Chemie
tub.publisher.universityorinstitutionTechnische Universität Berlin

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