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Iron-based pre-catalyst supported on polyformamidine for C-C bond formation

Enthaler, Stephan; Krackl, Sebastian; Epping, Jan Dirk; Eckhardt, Björn; Weidner, Steffen M.; Fischer, Anna

In the present study the incorporation of iron into an organic polymer, composed of formamidine subunits [R–N[double bond, length as m-dash]C(H)–NH–R], has been examined. The catalytic ability of the recyclable material was investigated in the iron-catalyzed formation of C–C bonds. After optimization of the reaction conditions, excellent yields and chemoselectivities were feasible.
Published in: Polymer chemistry, 10.1039/c2py00540a, Royal Society of Chemistry
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  • This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.