Die Kristallstruktur von Hexa-μ-chloro-μ4- oxo - tetrakis [hexamethy lentetramin - kupfer(II)] , [CU4Cl60(C6H12N4)4] , einem Kupfer(II)-Komplex mit Berylliumoxoacetat-ähnlicher Struktur

Pickardt, Joachim; Rautenberg, Norbert

Die Kristallstruktur von Hexa-μ-chloro-μ4- oxo - tetrakis [hexamethy lentetramin - kupfer(II)] , [CU4Cl60(C6H12N4)4] , einem Kupfer(II)-Komplex mit Berylliumoxoacetat-ähnlicher Struktur

dc.contributor.author	Pickardt, Joachim
dc.contributor.author	Rautenberg, Norbert
dc.date.accessioned	2019-01-02T14:02:55Z
dc.date.available	2019-01-02T14:02:55Z
dc.date.issued	1982
dc.description.abstract	By reaction of solutions of CuCl2·2H2O and hexamethylenetetramine, C6H12N4, in acetone, a complex [Cu4Cl6O(C6H12N4)] could be obtained as single crystals. An X-ray analysis shows that the complex has a structure related to that of basic beryllium acetate. An oxygen atom is tetrahedrally surrounded by four cop-per atoms which, together with six chlorine atoms, form an adamantane-like core. Each copper atom is bonded via a nitrogen atom to a hexamethylenetetramine molecule.	en
dc.identifier.eissn	1865-7117
dc.identifier.issn	0932-0776
dc.identifier.uri	https://depositonce.tu-berlin.de/handle/11303/8786
dc.identifier.uri	http://dx.doi.org/10.14279/depositonce-7915
dc.language.iso	de
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc	540 Chemie und zugeordnete Wissenschaften	de
dc.subject.other	copper(II)complexes	en
dc.subject.other	chloro complexes	en
dc.subject.other	hexamethylenetetramine	en
dc.subject.other	x-ray	en
dc.title	Die Kristallstruktur von Hexa-μ-chloro-μ4- oxo - tetrakis [hexamethy lentetramin - kupfer(II)] , [CU4Cl60(C6H12N4)4] , einem Kupfer(II)-Komplex mit Berylliumoxoacetat-ähnlicher Struktur	de
dc.title.translated	The Crystal Structure of Hexa-μ-chloro-μ4- oxo-tetrakis [hexamethylenetetraminecopper- (II)], [Cu4Cl6O(C6H12N4)4], a Copper(II) Complex with a Structure Related to that of Beryllium Oxoacetate	de
dc.type	Article	en
dc.type.version	publishedVersion	en
dcterms.bibliographicCitation.doi	10.1515/znb-1982-1027
dcterms.bibliographicCitation.issue	10
dcterms.bibliographicCitation.journaltitle	Zeitschrift für Naturforschung B	de
dcterms.bibliographicCitation.originalpublishername	De Gruyter	en
dcterms.bibliographicCitation.originalpublisherplace	Berlin
dcterms.bibliographicCitation.pageend	1357
dcterms.bibliographicCitation.pagestart	1355
dcterms.bibliographicCitation.volume	37
tub.accessrights.dnb	free
tub.affiliation	Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Anorganische Chemie - Festkörper- und Materialchemie	de
tub.affiliation.faculty	Fak. 2 Mathematik und Naturwissenschaften	de
tub.affiliation.group	FG Anorganische Chemie - Festkörper- und Materialchemie	de
tub.affiliation.institute	Inst. Chemie	de
tub.publisher.universityorinstitution	Technische Universität Berlin	de

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