Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes
dc.contributor.author | Zhang, Liangliang | |
dc.contributor.author | Oestreich, Martin | |
dc.date.accessioned | 2022-03-31T07:00:51Z | |
dc.date.available | 2022-03-31T07:00:51Z | |
dc.date.issued | 2021-07-16 | |
dc.date.updated | 2022-03-21T03:14:38Z | |
dc.description.abstract | A nickel/zinc‐catalyzed cross‐electrophile coupling of alkyl electrophiles activated by an α‐cyano group and chlorosilanes is reported. Elemental zinc is the stoichiometric reductant in this reductive coupling process. By this, a C(sp3)−Si bond can be formed starting from two electrophilic reactants whereas previous methods rely on the combination of carbon nucleophiles and silicon electrophiles or vice versa. | en |
dc.description.sponsorship | TU Berlin, Open-Access-Mittel – 2021 | |
dc.identifier.eissn | 1521-3773 | |
dc.identifier.issn | 1433-7851 | |
dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/16618 | |
dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-15395 | |
dc.language.iso | en | en |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | en |
dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
dc.subject.other | cross-coupling | en |
dc.subject.other | nickel | en |
dc.subject.other | silicon | en |
dc.subject.other | synthetic methods | en |
dc.subject.other | zinc | en |
dc.title | Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes | en |
dc.type | Article | en |
dc.type.version | publishedVersion | en |
dcterms.bibliographicCitation.doi | 10.1002/anie.202107492 | en |
dcterms.bibliographicCitation.issue | 34 | en |
dcterms.bibliographicCitation.journaltitle | Angewandte Chemie International Edition | en |
dcterms.bibliographicCitation.originalpublishername | Wiley | en |
dcterms.bibliographicCitation.originalpublisherplace | New York, NY | en |
dcterms.bibliographicCitation.pageend | 18590 | en |
dcterms.bibliographicCitation.pagestart | 18587 | en |
dcterms.bibliographicCitation.volume | 60 | en |
tub.accessrights.dnb | free | en |
tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Organische Chemie / Synthese und Katalyse | de |
tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
tub.affiliation.group | FG Organische Chemie / Synthese und Katalyse | de |
tub.affiliation.institute | Inst. Chemie | de |
tub.publisher.universityorinstitution | Technische Universität Berlin | en |