Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes
| dc.contributor.author | Zhang, Liangliang | |
| dc.contributor.author | Oestreich, Martin | |
| dc.date.accessioned | 2022-03-31T07:00:51Z | |
| dc.date.available | 2022-03-31T07:00:51Z | |
| dc.date.issued | 2021-07-16 | |
| dc.date.updated | 2022-03-21T03:14:38Z | |
| dc.description.abstract | A nickel/zinc‐catalyzed cross‐electrophile coupling of alkyl electrophiles activated by an α‐cyano group and chlorosilanes is reported. Elemental zinc is the stoichiometric reductant in this reductive coupling process. By this, a C(sp3)−Si bond can be formed starting from two electrophilic reactants whereas previous methods rely on the combination of carbon nucleophiles and silicon electrophiles or vice versa. | en |
| dc.description.sponsorship | TU Berlin, Open-Access-Mittel – 2021 | |
| dc.identifier.eissn | 1521-3773 | |
| dc.identifier.issn | 1433-7851 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/16618 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-15395 | |
| dc.language.iso | en | en |
| dc.rights | This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. | |
| dc.rights | ||
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | en |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.subject.other | cross-coupling | en |
| dc.subject.other | nickel | en |
| dc.subject.other | silicon | en |
| dc.subject.other | synthetic methods | en |
| dc.subject.other | zinc | en |
| dc.title | Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes | en |
| dc.type | Article | en |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1002/anie.202107492 | en |
| dcterms.bibliographicCitation.issue | 34 | en |
| dcterms.bibliographicCitation.journaltitle | Angewandte Chemie International Edition | en |
| dcterms.bibliographicCitation.originalpublishername | Wiley | en |
| dcterms.bibliographicCitation.originalpublisherplace | New York, NY | en |
| dcterms.bibliographicCitation.pageend | 18590 | en |
| dcterms.bibliographicCitation.pagestart | 18587 | en |
| dcterms.bibliographicCitation.volume | 60 | en |
| tub.accessrights.dnb | free | en |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Organische Chemie / Synthese und Katalyse | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.group | FG Organische Chemie / Synthese und Katalyse | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin | en |