A Ru-Complex Tethered to a N-Rich Covalent Triazine Framework for Tandem Aerobic Oxidation-Knoevenagel Condensation Reactions

dc.contributor.authorWatson, Geert
dc.contributor.authorGohari Derakhshandeh, Parviz
dc.contributor.authorAbednatanzi, Sara
dc.contributor.authorSchmidt, Johannes
dc.contributor.authorLeus, Karen
dc.contributor.authorVan Der Voort, Pascal
dc.date.accessioned2021-03-10T08:03:35Z
dc.date.available2021-03-10T08:03:35Z
dc.date.issued2021-02-05
dc.date.updated2021-03-02T19:42:22Z
dc.description.abstractHerein, a highly N-rich covalent triazine framework (CTF) is applied as support for a RuIII complex. The bipyridine sites within the CTF provide excellent anchoring points for the [Ru(acac)2(CH3CN)2]PF6 complex. The obtained robust RuIII@bipy-CTF material was applied for the selective tandem aerobic oxidation-Knoevenagel condensation reaction. The presented system shows a high catalytic performance (>80% conversion of alcohols to α, β-unsaturated nitriles) without the use of expensive noble metals. The bipy-CTF not only acts as the catalyst support but also provides the active sites for both aerobic oxidation and Knoevenagel condensation reactions. This work highlights a new perspective for the development of highly efficient and robust heterogeneous catalysts applying CTFs for cascade catalysis.en
dc.identifier.eissn1420-3049
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/12767
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-11567
dc.language.isoenen
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.othercovalent triazine frameworksen
dc.subject.otherheterogeneous catalysisen
dc.subject.othertandem catalysisen
dc.subject.otheraerobic oxidation-knoevenagel condensationen
dc.titleA Ru-Complex Tethered to a N-Rich Covalent Triazine Framework for Tandem Aerobic Oxidation-Knoevenagel Condensation Reactionsen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.articlenumber838en
dcterms.bibliographicCitation.doi10.3390/molecules26040838en
dcterms.bibliographicCitation.issue4en
dcterms.bibliographicCitation.journaltitleMoleculesen
dcterms.bibliographicCitation.originalpublishernameMDPIen
dcterms.bibliographicCitation.originalpublisherplaceBaselen
dcterms.bibliographicCitation.volume26en
tub.accessrights.dnbfreeen
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Funktionsmaterialiende
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Funktionsmaterialiende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinen

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