Transfer hydrosilylation

dc.contributor.authorOestreich, Martin
dc.date.accessioned2017-07-14T11:38:56Z
dc.date.available2017-07-14T11:38:56Z
dc.date.issued2016
dc.description.abstractTransfer hydrogenation is without question a common technology in industry and academia. Unlike its countless varieties, conceptually related transfer hydrosilylations had essentially been unreported until the recent development of a radical and an ionic variant. The new methods are both based on a silicon-substituted cyclohexa-1,4-diene and hinge on the aromatization of the corresponding cyclohexadienyl radical and cation intermediates, respectively, concomitant with homo-or heterolytic fission of the Si-C bond. Both the radical and ionic transfer hydrosilylation are brought into context with one other in this Minireview, and early insight into the possibility of transfer hydrosilylation is included. Although the current state-of-the-art is certainly still limited, the recent advances have already revealed the promising potential of transfer hydrosilylation.en
dc.identifier.eissn1521-3773
dc.identifier.issn1433-7851
dc.identifier.urihttp://depositonce.tu-berlin.de/handle/11303/6503
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-6011
dc.language.isoenen
dc.relation.referenceshttp://dx.doi.org/10.14279/depositonce-6012en
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.othercationsen
dc.subject.othercyclohexa-1,4-dienesen
dc.subject.otherhydrosilylationen
dc.subject.otherradicalsen
dc.subject.othersilane transferen
dc.titleTransfer hydrosilylationen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1002/anie.201508879en
dcterms.bibliographicCitation.issue2en
dcterms.bibliographicCitation.journaltitleAngewandte Chemie - International Editionen
dcterms.bibliographicCitation.originalpublishernameWiley-VCHen
dcterms.bibliographicCitation.originalpublisherplaceWeinheimen
dcterms.bibliographicCitation.pageend499en
dcterms.bibliographicCitation.pagestart494en
dcterms.bibliographicCitation.volume55en
tub.accessrights.dnbfreeen
tub.affiliationFak. 2 Mathematik und Naturwissenschaften>Inst. Chemie>FG Organische Chemie / Synthese und Katalysede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Organische Chemie / Synthese und Katalysede
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinen
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