Thumbnail Image
🆕 Date Issued:
1980
🗄 Date Available:2019-01-04
Article

Please use this identifier to cite or link to this item:

Di-μ-iodo-bis [dicarbonyl(di-tert-butylphosphin)ruthenium(I)] (Ru-Ru) und Bis(tri-tert-butylphosphonium)-di-μ-iodo-bis[carbonyl-diiodo- (di-tert-butylphosphin)ruthenium(II)]

Schumann, Herbert; Opitz, Joachim

FG Anorganische Chemie - Festkörper- und Materialchemie

[(t-C4H9)3PH]2[{Ru(μI)I2(CO)[P(t-C4H9)2H]}2] is prepared by the reaction of RUC13 · (H2O)x with CO, NaI, and P(t-C4H9)3 in 2-methoxyethanol. Its IR, Raman, and NMR spectra are reported and discussed. [Ru(μ-I)(CO)2P(t-C4H9)2H)2 is obtained by the reaction of [Ru(μ-I)I(CO)3]2 with P(t-C4H9)3 in 2-methoxyethanol. The X18MAA′M′X′18 spin system of its 1H NMR spectrum is analysed.
ruthenium(i) complexdi-tert-butylphosphinenmr spectra;ruthenium(ii) complextri-tert-butylphosphonium salt
Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)
Full item page