Substituted bisphosphanylamines as ligands in gold(I) chemistry – synthesis and structures

dc.contributor.authorWiedemann, Dennis
dc.contributor.authorGamer, Michael T.
dc.contributor.authorRoesky, Peter W.
dc.date.accessioned2016-09-13T12:02:44Z
dc.date.available2016-09-13T12:02:44Z
dc.date.issued2009
dc.description.abstractDimethyl 5-aminoisophthalate, which is a building block of amino-substituted tetralactam macrocycles, was used as ligand in gold(I) chemistry to form model complexes for macrocyclic gold compounds. Reaction of dimethyl 5-aminoisophthalate with chlorodiphenylphosphine gave the diphosphine compound dimethyl 5-[N,N-bis(diphenylphosphanyl)amino]isophthalate (dmbpaip). This compound can further be reacted with [AuCl(tht)] (tht = tetrahydrothiophene) to give the dinuclear complex [Au(2),Cl(2)(dmbpaip)]. In contrast, treatment of dinbpaip with [Au(tht)(2)]ClO(4) resulted in the ionic compound [Au(2)(dmbpaip)(2)](ClO(4))(2) in which the cation forms an eight-membered Au(2)P(4)N(2) heterocycle. In both gold(I) compounds Au center dot center dot center dot Au interactions are observed. All new compounds were characterized by single-crystal X-ray diffraction.en
dc.identifier.eissn1521-3749
dc.identifier.issn0044-2313
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/5895
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-5488
dc.language.isoen
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.othergolden
dc.subject.otherchelatesen
dc.subject.otherN-P ligandsen
dc.subject.otherP ligandsen
dc.titleSubstituted bisphosphanylamines as ligands in gold(I) chemistry – synthesis and structuresen
dc.typeArticleen
dc.type.versionacceptedVersionen
dcterms.bibliographicCitation.doi10.1002/zaac.200800368
dcterms.bibliographicCitation.issue1
dcterms.bibliographicCitation.journaltitleZeitschrift für anorganische und allgemeine Chemieen
dcterms.bibliographicCitation.originalpublishernameWiley-VCHen
dcterms.bibliographicCitation.originalpublisherplaceWeinheimen
dcterms.bibliographicCitation.pageend129
dcterms.bibliographicCitation.pagestart125
dcterms.bibliographicCitation.volume635
tub.accessrights.dnbdomain
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Anorganische Chemie - Festkörper- und Materialchemiede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Anorganische Chemie - Festkörper- und Materialchemiede
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlin

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