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🆕 Date Issued:
2015
🗄 Date Available:2017-10-25
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Surface enhanced vibrational spectroscopic evidence for an alternative DNA-independent redox activation of endonuclease III

Moe, Elin; Sezer, Murat; Hildebrandt, Peter; Todorovic, Smilja

FG Physikalische Chemie / Biophysikalische Chemie

Surface enhanced vibrational spectro-electrochemistry of endonuclease III provides direct evidence that the [4Fe-4S] cluster is responsible for the enzyme redox activity, and that this process is not exclusively DNA-mediated, as currently proposed. We report the first surface enhanced resonance Raman spectrum of a [4Fe-4S](2+) cluster containing enzyme.
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  • This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
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