Isolation of a germanium(II) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato ligand

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dc.contributor.authorOchiai, Tatsumi
dc.contributor.authorFranz, Daniel
dc.contributor.authorWu, Xiao-Nan
dc.contributor.authorInoue, Shigeyoshi
dc.date.accessioned2017-10-25T06:27:16Z
dc.date.available2017-10-25T06:27:16Z
dc.date.issued2015
dc.descriptionDieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.de
dc.descriptionThis publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.en
dc.description.abstractThe novel amino(imino)germylene 1 was prepared by the conversion of HNIPr (NIPr = bis(2,6-diisopropylphenyl) imidazolin-2-imino) with 1 equiv. of Ge[N(SiMe3)(2)](2). Germylene 1 reacts with B (C6F5)(3) to afford the borate salt 2(+)[MeB(C6F5)(3)](-) in a methyl-abstraction and ring-closing reaction. The conversion of 2 with Fe-2(CO)(9) furnishes the germylene iron carbonyl complex 3 with a trigonal planar-coordinate germanium atom.en
dc.identifier.eissn1477-9234
dc.identifier.issn1477-9226
dc.identifier.pmid26011737
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/6951
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-6290
dc.language.isoen
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.titleIsolation of a germanium(II) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato liganden
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/c5dt01554e
dcterms.bibliographicCitation.issue24
dcterms.bibliographicCitation.journaltitleDalton transactionsen
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistryde
dcterms.bibliographicCitation.originalpublisherplaceCambridgede
dcterms.bibliographicCitation.pageend10956
dcterms.bibliographicCitation.pagestart10952
dcterms.bibliographicCitation.volume44
tub.accessrights.dnbdomain
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Anorganische Chemie - Festkörper- und Materialchemiede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Anorganische Chemie - Festkörper- und Materialchemiede
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlin

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