Comparison of phase transfer agents in the aqueous biphasic hydroformylation of higher alkenes

dc.contributor.authorNowothnick, Henriette
dc.contributor.authorRost, Anke
dc.contributor.authorHamerla, Tobias
dc.contributor.authorSchomäcker, Reinhard
dc.contributor.authorMüller, Christian
dc.contributor.authorVogt, Dieter
dc.date.accessioned2016-06-22T08:05:24Z
dc.date.available2016-06-22T08:05:24Z
dc.date.issued2013
dc.descriptionDieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.de
dc.descriptionThis publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.en
dc.description.abstractThe Rh-catalyzed aqueous biphasic hydroformylation with the bidentate ligand SulfoXantPhos was investigated for different phase transfer agents (PTA). As such, polymer latices and microemulsions formed by non-ionic surfactants were used. In general, a higher PTA concentration enhances the reaction progress. The feasibility of catalyst recycling by simple phase separation is shown in principle. The Rh losses are low in the surfactant system and promising for a technical approach.en
dc.description.sponsorshipEC/FP7/215193/EU/Homogeneous supported catalyst technologies: the sustainable approach to highly-selective, fine chemicals production/NANO-HOSTen
dc.description.sponsorshipDFG, TRR 63, Integrierte chemische Prozesse in flüssigen Mehrphasensystemenen
dc.identifier.eissn2044-4753
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/5585
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-5214
dc.language.isoen
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.titleComparison of phase transfer agents in the aqueous biphasic hydroformylation of higher alkenesen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/c2cy20629c
dcterms.bibliographicCitation.issue3
dcterms.bibliographicCitation.journaltitleCatalysis science & technology : a multidisciplinary journal focussing on all fundamental science and technological aspects of catalysisen
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistryde
dcterms.bibliographicCitation.originalpublisherplaceCambridgede
dcterms.bibliographicCitation.pageend605
dcterms.bibliographicCitation.pagestart600
dcterms.bibliographicCitation.volume3
tub.accessrights.dnbdomain
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Mehrphasenreaktionstechnikde
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Mehrphasenreaktionstechnikde
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlin

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