Untersuchungen Über Iodomercurate: Kristallstrukturen Von Bis-Tetramethylammonium-Tetraiodomercurat(Ii), Tetramethylammoniumpentaiododimercurat(Ii) Und Bis[Di(12-Krone-4)Lithium]-Decaiodotetramercurat(Ii)

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dc.contributor.authorPickardt, Joachim
dc.contributor.authorWiese, Sven
dc.contributor.authorBorowski, Marina
dc.date.accessioned2018-10-10T07:34:39Z
dc.date.available2018-10-10T07:34:39Z
dc.date.issued2006
dc.description.abstractCrystals of [Me4N]2[HgI4] (1) and [Me4N][Hg2I5] (2), were obtained from solutions of stoichiometric amounts of HgI2 and Me4NI in EtOH or acetone, resp., while crystals of [Li(12-crown- 4)2]2[Hg4I10] (3) formed upon interdiffusion of methanolic solutions of HgI2, LiI and of the auxiliary ligand. The crystal structures of the compounds were determined. The [Hg2I5]− ion in (2) has a polymeric sheet structure, built up from [Hg2I6] units bridged by [HgI4] groups sharing common apices. The [Hg4I10]2− ion in 3 consists of four [HgI4] tetrahedra sharing common edges. A short survey on the iodomercurate(II) anions known up to now is given and a classification is proposeden
dc.identifier.eissn1865-7117
dc.identifier.issn0932-0776
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/8312
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-7463
dc.language.isode
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.otherMercuryen
dc.subject.otherIodomercurate(II) Anionsen
dc.subject.otherPentaiododimercurateen
dc.subject.otherDecaiodotetramercurateen
dc.subject.othercrystal structuresen
dc.titleUntersuchungen Über Iodomercurate: Kristallstrukturen Von Bis-Tetramethylammonium-Tetraiodomercurat(Ii), Tetramethylammoniumpentaiododimercurat(Ii) Und Bis[Di(12-Krone-4)Lithium]-Decaiodotetramercurat(Ii)de
dc.title.translatedInvestigations on Iodomercurates: Crystal Structures of Bis-tetramethylammoniumtetraiodomercurate(II), Tetramethylammonium pentaiododimercurate(II) andBis[di(12-crown-4)lithium] decaiodotetramercurate(II)en
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1515/znb-2006-0802
dcterms.bibliographicCitation.issue8
dcterms.bibliographicCitation.journaltitleZeitschrift für Naturforschung Bde
dcterms.bibliographicCitation.originalpublishernameDe Gruyteren
dcterms.bibliographicCitation.originalpublisherplaceBerlinen
dcterms.bibliographicCitation.pageend941
dcterms.bibliographicCitation.pagestart935
dcterms.bibliographicCitation.volume61
tub.accessrights.dnbfree
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemiede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinde

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