A cobalt arylphosphonate MOF – superior stability, sorption and magnetism

dc.contributor.authorZorlu, Yunus
dc.contributor.authorErbahar, Doğan
dc.contributor.authorÇetinkaya, Ahmet
dc.contributor.authorBulut, Aysun
dc.contributor.authorErkal, Turan S.
dc.contributor.authorYazaydin, A. Ozgur
dc.contributor.authorBeckmann, Jens
dc.contributor.authorYücesan, Gündoğ
dc.date.accessioned2020-06-15T06:23:53Z
dc.date.available2020-06-15T06:23:53Z
dc.date.issued2019-01-25
dc.description.abstractWe report a novel metal-organic framework (MOF) based on a cobalt arylphosphonate, namely, [Co2(H4-MTPPA)]·3NMP·H2O (1·3NMP·H2O), which was prepared solvothermically from the tetrahedral linker tetraphenylmethane tetrakis-4-phosphonic acid (H8-MTPPA) and CoSO4·7H2O in N-methyl-2-pyrrolidone (NMP). Compound 1 has the highest porosity (BET surface area of 1034 m2 g−1) ever reported for a MOF based on an aryl phosphonic acid linker. The indigo blue crystals of 1·3NMP·H2O are composed of edge-shared eight-membered Co2P2O4 rings, and are thermally very stable up to 500 °C.en
dc.description.sponsorshipTU Berlin, Open-Access-Mittel - 2019en
dc.identifier.eissn1364-548X
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/11332
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-10219
dc.language.isoenen
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.otherBET surface areasen
dc.subject.othermetal-organic frameworken
dc.subject.otherMOFen
dc.subject.othercobalt arylphosphonateen
dc.titleA cobalt arylphosphonate MOF – superior stability, sorption and magnetismen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/C8CC09655Den
dcterms.bibliographicCitation.journaltitleChemical Communicationsen
dcterms.bibliographicCitation.originalpublishernameRSC Publishingen
dcterms.bibliographicCitation.originalpublisherplaceCambridgeen
dcterms.bibliographicCitation.pageend3056en
dcterms.bibliographicCitation.pagestart3053en
dcterms.bibliographicCitation.volume55en
tub.accessrights.dnbfreeen
tub.affiliationFak. 3 Prozesswissenschaften>Inst. Lebensmitteltechnologie und Lebensmittelchemie>FG Lebensmittelchemie und Toxikologiede
tub.affiliation.facultyFak. 3 Prozesswissenschaftende
tub.affiliation.groupFG Lebensmittelchemie und Toxikologiede
tub.affiliation.instituteInst. Lebensmitteltechnologie und Lebensmittelchemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinen
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