Mass analyzed threshold ionization spectra of phenol⋯Ar2: ionization energy and cation intermolecular vibrational frequencies

dc.contributor.authorArmentano, Antonio
dc.contributor.authorTong, Xin
dc.contributor.authorRiese, Mikko
dc.contributor.authorPimblott, Simon M.
dc.contributor.authorMüller-Dethlefs, Klaus
dc.contributor.authorFujii, Masaaki
dc.contributor.authorDopfer, Otto
dc.date.accessioned2016-07-01T06:27:32Z
dc.date.available2016-07-01T06:27:32Z
dc.date.issued2011
dc.descriptionDieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.de
dc.descriptionThis publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.en
dc.description.abstractThe phenol+⋯Ar2 complex has been characterized in a supersonic jet by mass analyzed threshold ionization (MATI) spectroscopyvia different intermediate intermolecular vibrational states of the first electronically excited state (S1). From the spectra recorded via the S100 origin and the S1βx intermolecular vibrational state, the ionization energy (IE) has been determined as 68 288 ± 5 cm−1, displaying a red shift of 340 cm−1 from the IE of the phenol+ monomer. Well-resolved, nearly harmonic vibrational progressions with a fundamental frequency of 10 cm−1 have been observed in the ion ground state (D0) and assigned to the symmetric van der Waals (vdW) bending mode, βx, along the x axis containing the C–O bond. MATI spectra recorded via the S1 state involving other higher-lying intermolecular vibrational states (σ1s, β3x, σ1sβ1x, σ1sβ2x) are characterized by unresolved broad structures.en
dc.identifier.eissn1463-9084
dc.identifier.issn1463-9076
dc.identifier.pmid21063583
dc.identifier.urihttp://depositonce.tu-berlin.de/handle/11303/5749
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-5369
dc.language.isoen
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.titleMass analyzed threshold ionization spectra of phenol⋯Ar2: ionization energy and cation intermolecular vibrational frequenciesen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/c004497k
dcterms.bibliographicCitation.issue13
dcterms.bibliographicCitation.journaltitlePhysical chemistry, chemical physicsen
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistryde
dcterms.bibliographicCitation.originalpublisherplaceCambridgede
dcterms.bibliographicCitation.pageend6076
dcterms.bibliographicCitation.pagestart6071
dcterms.bibliographicCitation.volume13
tub.accessrights.dnbdomain
tub.affiliationFak. 2 Mathematik und Naturwissenschaften>Inst. Optik und Atomare Physikde
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.instituteInst. Optik und Atomare Physikde
tub.publisher.universityorinstitutionTechnische Universität Berlin
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