Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks
| dc.contributor.author | Trunk, Matthias Georg | |
| dc.contributor.author | Teichert, Johannes F. | |
| dc.contributor.author | Thomas, Arne | |
| dc.date.accessioned | 2019-04-02T15:27:11Z | |
| dc.date.available | 2019-04-02T15:27:11Z | |
| dc.date.issued | 2017 | |
| dc.description.abstract | Porous polymer networks based on sterically encumbered triphenylphosphine motifs, mimicking the basic sites employed in frustrated Lewis pair (FLP) chemistry, were synthesized via Yamamoto polymerization and their interactions with the strong Lewis acid B(C6F5)3 probed. The combinations yield semi-immobilized FLPs, which are able to cleave dihydrogen heterolytically at ambient temperature and low hydrogen pressure. | en |
| dc.description.sponsorship | DFG, 53182490, EXC 314: Unifying Concepts in Catalysis | en |
| dc.description.sponsorship | EC/FP7/278593/EU/Organic Zeolites/ORGZEO | en |
| dc.identifier.eissn | 1520-5126 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/9253 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-8330 | |
| dc.language.iso | en | en |
| dc.relation.ispartof | 10.14279/depositonce-7165 | |
| dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | en |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.subject.other | frustrated Lewis pairs | en |
| dc.subject.other | microporous polymer networks | en |
| dc.subject.other | room-temperature | en |
| dc.subject.other | activation | en |
| dc.subject.other | hydrogen | en |
| dc.title | Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks | en |
| dc.type | Article | en |
| dc.type.version | acceptedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1021/jacs.6b13147 | en |
| dcterms.bibliographicCitation.issue | 10 | en |
| dcterms.bibliographicCitation.journaltitle | Journal of the American Chemical Society | en |
| dcterms.bibliographicCitation.originalpublishername | American Chemical Society | en |
| dcterms.bibliographicCitation.originalpublisherplace | Washington, DC | en |
| dcterms.bibliographicCitation.pageend | 3618 | en |
| dcterms.bibliographicCitation.pagestart | 3615 | en |
| dcterms.bibliographicCitation.volume | 139 | en |
| tub.accessrights.dnb | domain | en |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Funktionsmaterialien | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.group | FG Funktionsmaterialien | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin | en |