Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks

dc.contributor.authorTrunk, Matthias Georg
dc.contributor.authorTeichert, Johannes F.
dc.contributor.authorThomas, Arne
dc.date.accessioned2019-04-02T15:27:11Z
dc.date.available2019-04-02T15:27:11Z
dc.date.issued2017
dc.description.abstractPorous polymer networks based on sterically encumbered triphenylphosphine motifs, mimicking the basic sites employed in frustrated Lewis pair (FLP) chemistry, were synthesized via Yamamoto polymerization and their interactions with the strong Lewis acid B(C6F5)3 probed. The combinations yield semi-immobilized FLPs, which are able to cleave dihydrogen heterolytically at ambient temperature and low hydrogen pressure.en
dc.description.sponsorshipDFG, 53182490, EXC 314: Unifying Concepts in Catalysisen
dc.description.sponsorshipEC/FP7/278593/EU/Organic Zeolites/ORGZEOen
dc.identifier.eissn1520-5126
dc.identifier.issn0002-7863
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/9253
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-8330
dc.language.isoenen
dc.relation.ispartof10.14279/depositonce-7165
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.otherfrustrated Lewis pairsen
dc.subject.othermicroporous polymer networksen
dc.subject.otherroom-temperatureen
dc.subject.otheractivationen
dc.subject.otherhydrogenen
dc.titleRoom-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networksen
dc.typeArticleen
dc.type.versionacceptedVersionen
dcterms.bibliographicCitation.doi10.1021/jacs.6b13147en
dcterms.bibliographicCitation.issue10en
dcterms.bibliographicCitation.journaltitleJournal of the American Chemical Societyen
dcterms.bibliographicCitation.originalpublishernameAmerican Chemical Societyen
dcterms.bibliographicCitation.originalpublisherplaceWashington, DCen
dcterms.bibliographicCitation.pageend3618en
dcterms.bibliographicCitation.pagestart3615en
dcterms.bibliographicCitation.volume139en
tub.accessrights.dnbdomainen
tub.affiliationFak. 2 Mathematik und Naturwissenschaften>Inst. Chemie>FG Funktionsmaterialiende
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Funktionsmaterialiende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinen
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