Synthesis and Crystal Structure of the New Telluric Acid Adduct (RbCl)3·Te(OH)6

dc.contributor.authorMahlmeister, Dirk
dc.contributor.authorIrran, Elisabeth
dc.date.accessioned2018-10-01T08:01:20Z
dc.date.available2018-10-01T08:01:20Z
dc.date.issued2012
dc.description.abstractThe new telluric acid adduct (RbCl)3 ・ Te(OH)6 was prepared by dissolving RbCl and Te(OH)6 in the molar ratio of 3 : 1 in deionized water at r. t. and slow evaporation of the solvent in air. The crystal structure of the colorless crystals was determined with single-crystal X-ray diffraction (trigonal space group: R3̄c (no. 167), a = 14.4392(8), c = 10.4301(16) Å , Z = 6). In (RbCl)3 ・ Te(OH)6, the rubidium atom is surrounded by five chlorine and four oxygen atoms in form of an irregular tricapped trigonal prism. Each tellurium atom is octahedrally surrounded by six oxygen atoms. The Te(OH)6 octahedra and the RbCl5O4 polyhedra are linked to a dense three-dimensional network which is additionally strengthened by hydrogen bonds.en
dc.identifier.eissn1865-7117
dc.identifier.issn0932-0776
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/8220
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-7371
dc.language.isoen
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.otherrubidium chlorideen
dc.subject.othertelluric aciden
dc.subject.othercrystal structureen
dc.titleSynthesis and Crystal Structure of the New Telluric Acid Adduct (RbCl)3·Te(OH)6en
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1515/znb-2012-0101
dcterms.bibliographicCitation.issue1
dcterms.bibliographicCitation.journaltitleZeitschrift für Naturforschung Ben
dcterms.bibliographicCitation.originalpublishernameDe Gruyteren
dcterms.bibliographicCitation.originalpublisherplaceBerlinen
dcterms.bibliographicCitation.pageend4
dcterms.bibliographicCitation.pagestart1
dcterms.bibliographicCitation.volume67
tub.accessrights.dnbfree
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemiede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinde

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