Tuning of gallery heights in a crystalline 2D carbon nitride network

Simple item page
dc.contributor.authorChong, Samantha Y.
dc.contributor.authorJones, James T. A.
dc.contributor.authorKhimyak, Yaroslav Z.
dc.contributor.authorCooper, Andrew I.
dc.contributor.authorThomas, Arne
dc.contributor.authorAntonietti, Markus
dc.contributor.authorBojdys, Michael J.
dc.date.accessioned2016-06-27T09:43:30Z
dc.date.available2016-06-27T09:43:30Z
dc.date.issued2013
dc.descriptionDieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.de
dc.descriptionThis publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.en
dc.description.abstractPoly(triazine imide)—a 2D layered network—can be obtained as an intercalation compound with halides from the ionothermal condensation of dicyandiamide in a eutectic salt melt. The gallery height of the intercalated material can be tuned via the composition of the eutectic melt and by post-synthetic modification. Here, we report the synthesis of poly(triazine imide) with intercalated bromide ions (PTI/Br) from a lithium bromide and potassium bromide salt melt. PTI/Br has a hexagonal unit-cell (P63cm (no. 185); a = 8.500390(68) Å, c = 7.04483(17) Å) that contains two layers of imide-bridged triazine (C3N3) units stacked in an AB-fashion as corroborated by solid-state NMR, FTIR spectroscopy and high-resolution TEM. By comparison with a recently reported material PTI/Li+Cl−, prepared from a LiCl/KCl eutectic, the layer-stacking distance in the analogous bromide material was expanded from 3.38 Å to 3.52 Å – an exceptionally large spacing for an aromatic, discotic system (cf. graphite 3.35 Å). Subsequent treatment of PTI/Br with concentrated ammonium fluoride yields poly(triazine imide) with intercalated fluoride ions (PTI/F) (P63/m (no. 176); a = 8.4212(4) Å, c = 6.6381(5) Å) as a statistical phase mix with PTI/Br. Fluoride intercalation leads to a contraction of the gallery height to 3.32 Å, demonstrating that the gallery height is synthetically tuneable in these materials.en
dc.identifier.eissn2050-7488
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/5667
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-5287
dc.language.isoen
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.ddc530 Physikde
dc.titleTuning of gallery heights in a crystalline 2D carbon nitride networken
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/c2ta01068b
dcterms.bibliographicCitation.issue4
dcterms.bibliographicCitation.journaltitleJournal of materials chemistry : A, Materials for energy and sustainabilityen
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistryde
dcterms.bibliographicCitation.originalpublisherplaceCambridgede
dcterms.bibliographicCitation.pageend1107
dcterms.bibliographicCitation.pagestart1102
dcterms.bibliographicCitation.volume1
tub.accessrights.dnbdomain
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemiede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlin

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
c2ta01068b.pdf
Size:
823.8 KB
Format:
Adobe Portable Document Format
Download

Collections

Publications