Immobilization of an iridium pincer complex in a microporous polymer for application in room-temperature gas phase catalysis

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dc.contributor.authorKönig, Michaela
dc.contributor.authorRigo, Massimo
dc.contributor.authorChaoui, Nicolas
dc.contributor.authorNgoc, Trung Tran
dc.contributor.authorEpping, Jan Dirk
dc.contributor.authorSchmidt, Johannes
dc.contributor.authorPachfule, Pradip
dc.contributor.authorYe, Meng-Yang
dc.contributor.authorTrunk, Matthias
dc.contributor.authorTeichert, Johannes F.
dc.contributor.authorDrieß, Matthias
dc.contributor.authorThomas, Arne
dc.date.accessioned2021-06-03T13:46:08Z
dc.date.available2021-06-03T13:46:08Z
dc.date.issued2020-07-02
dc.description.abstractAn iridium dihydride pincer complex [IrH2(POCOP)] is immobilized in a hydroxy-functionalized microporous polymer network using the concepts of surface organometallic chemistry. The introduction of this novel, truly innocent support with remote OH-groups enables the formation of isolated active metal sites embedded in a chemically robust and highly inert environment. The catalyst maintained high porosity and without prior activation exhibited efficacy in the gas phase hydrogenation of ethene and propene at room temperature and low pressure. The catalyst can be recycled for at least four times.en
dc.description.sponsorshipDFG, 390540038, EXC 2008: Unifying Systems in Catalysis "UniSysCat"en
dc.description.sponsorshipTU Berlin, Open-Access-Mittel – 2020en
dc.identifier.eissn1521-3757
dc.identifier.issn0044-8249
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/13194
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-11989
dc.language.isoenen
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/en
dc.subject.ddc660 Chemische Verfahrenstechnikde
dc.subject.othercatalysisen
dc.subject.othergas phaseen
dc.subject.otherhydrogenationen
dc.subject.othermicroporous polymer networken
dc.subject.otherpinceren
dc.titleImmobilization of an iridium pincer complex in a microporous polymer for application in room-temperature gas phase catalysisen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1002/anie.202004092en
dcterms.bibliographicCitation.issue45en
dcterms.bibliographicCitation.journaltitleAngewandte Chemieen
dcterms.bibliographicCitation.originalpublishernameWileyen
dcterms.bibliographicCitation.originalpublisherplaceNew York, NYen
dcterms.bibliographicCitation.pageend19834en
dcterms.bibliographicCitation.pagestart19830en
dcterms.bibliographicCitation.volume59en
tub.accessrights.dnbfreeen
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Funktionsmaterialiende
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Funktionsmaterialiende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinen

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