Consecutive β,β′‐Selective C(sp3)−H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C6F5)3
| dc.contributor.author | Fang, Huaquan | |
| dc.contributor.author | Xie, Kaixue | |
| dc.contributor.author | Kemper, Sebastian | |
| dc.contributor.author | Oestreich, Martin | |
| dc.date.accessioned | 2021-06-25T12:21:02Z | |
| dc.date.available | 2021-06-25T12:21:02Z | |
| dc.date.issued | 2021-03-03 | |
| dc.date.updated | 2021-06-14T15:48:34Z | |
| dc.description.abstract | Tris(pentafluorophenyl)borane has been found to catalyze the two‐fold C(sp3)−H silylation of various trialkylamine derivatives with dihydrosilanes, furnishing the corresponding 4‐silapiperidines in decent yields. The multi‐step reaction cascade involves amine‐to‐enamine dehydrogenation at two alkyl residues and two electrophilic silylation reactions of those enamines, one inter‐ and one intramolecular. | en |
| dc.description.sponsorship | TU Berlin, Open-Access-Mittel – 2021 | |
| dc.identifier.eissn | 1521-3757 | |
| dc.identifier.issn | 0044-8249 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/13303 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-12095 | |
| dc.language.iso | en | en |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | en |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.subject.other | amines | en |
| dc.subject.other | boron | en |
| dc.subject.other | C−H activation | en |
| dc.subject.other | Si−H activation | en |
| dc.subject.other | silicon | en |
| dc.title | Consecutive β,β′‐Selective C(sp3)−H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C6F5)3 | en |
| dc.type | Article | en |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1002/anie.202016664 | en |
| dcterms.bibliographicCitation.issue | 15 | en |
| dcterms.bibliographicCitation.journaltitle | Angewandte Chemie International Edition | en |
| dcterms.bibliographicCitation.originalpublishername | Wiley | en |
| dcterms.bibliographicCitation.originalpublisherplace | New York, NY | en |
| dcterms.bibliographicCitation.pageend | 8546 | en |
| dcterms.bibliographicCitation.pagestart | 8542 | en |
| dcterms.bibliographicCitation.volume | 60 | en |
| tub.accessrights.dnb | free | en |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Organische Chemie / Synthese und Katalyse | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.group | FG Organische Chemie / Synthese und Katalyse | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin | en |