High-pressure behavior of disodered kesterite-type Cu2ZnSnS4
dc.contributor.author | Efthimiopoulos, Ilias | |
dc.contributor.author | Küllmey, Tim | |
dc.contributor.author | Speziale, Sergio | |
dc.contributor.author | Pakhomova, Anna S. | |
dc.contributor.author | Quennet, Marcel | |
dc.contributor.author | Paulus, Beate | |
dc.contributor.author | Ritscher, Anna | |
dc.contributor.author | Lerch, Martin | |
dc.date.accessioned | 2021-10-27T06:36:26Z | |
dc.date.available | 2021-10-27T06:36:26Z | |
dc.date.issued | 2021-07-22 | |
dc.description.abstract | We have investigated the high-pressure structural and vibrational behavior of the disordered kesterite-type Cu 2 ZnSnS 4 compound at ambient temperature. Our experimental and theoretical investigations have revealed a clear structural transition to a GeSb-type phase close to 15 GPa, a tetragonally distorted variant of the NaCl-type phase. The latter transformation is accompanied by a cationic coordination increase from fourfold to sixfold with respect to the sulfur anions. In addition, a change in the compressibility rate was detected at about 8 GPa within the pressure stability range of the disordered kesterite-type phase. Upon decompression, a disordered zinc blende/sphalerite structure is recovered. We discuss our findings in close conjunction with our recent high-pressure work on the ordered Cu 2 ZnSnS 4 modification. | en |
dc.identifier.eissn | 1432-0630 | |
dc.identifier.issn | 0947-8396 | |
dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/13761 | |
dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-12537 | |
dc.language.iso | en | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.subject.ddc | 530 Physik | de |
dc.subject.other | kesterite | en |
dc.subject.other | pressure | en |
dc.subject.other | Raman | en |
dc.subject.other | structure | en |
dc.subject.other | XRD | en |
dc.title | High-pressure behavior of disodered kesterite-type Cu2ZnSnS4 | en |
dc.type | Article | en |
dc.type.version | publishedVersion | en |
dcterms.bibliographicCitation.articlenumber | 616 | |
dcterms.bibliographicCitation.doi | 10.1007/s00339-021-04745-w | |
dcterms.bibliographicCitation.issue | 8 | |
dcterms.bibliographicCitation.journaltitle | Applied Physics A: Materials Science and Processing | en |
dcterms.bibliographicCitation.originalpublishername | Springer | en |
dcterms.bibliographicCitation.originalpublisherplace | Berlin [u.a.] | en |
dcterms.bibliographicCitation.volume | 127 | |
tub.accessrights.dnb | free | |
tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Anorganische Chemie - Festkörper- und Materialchemie | de |
tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
tub.affiliation.group | FG Anorganische Chemie - Festkörper- und Materialchemie | de |
tub.affiliation.institute | Inst. Chemie | de |
tub.publisher.universityorinstitution | Technische Universität Berlin | de |
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