Metallkomplexe mit 1,4,7-Trithiacyclononan: Kristallstrukturen von [CdI2 · C6H12S3]2 und [Hg(C6H12S3)2](HgI3)2

dc.contributor.authorPickardt, Joachim
dc.contributor.authorShen, Jing
dc.date.accessioned2018-11-10T16:38:19Z
dc.date.available2018-11-10T16:38:19Z
dc.date.issued1993
dc.description.abstractCrystals of the complexes [CdI2 · C6H12S3]2 (1) and [Hg(C6H12S3)2](HgI3)2 (2) were obtained by diffusion of 1,4,7-trithiacyclononane (9 S 3) in ethanol into aqueous solutions of cadmium iodide and mercuric iodide/potassium iodide, resp. Both compounds crystallize monoclinically,1: space group P21/n, Z = 4, a = 1207.1(5), b = 909.9(2), c = 1240.3(7) pm, β = 92.59(9)°; 2: P21/c, Z = 2, a = 804.7(6), b = 934.0(6), c = 2167.9(4) pm, β = 94.34(7)°. 1 is dimeric, consisting of two [CdI2 · 9S3] units, connected via iodine bridges. Crystals of 2 contain sandwich-like cations [Hg(9S3)2]2+ and [HgI3]- anions, forming chains via Hg ··· S and Hg ··· I bridges.en
dc.identifier.eissn1865-7117
dc.identifier.issn0932-0776
dc.identifier.urihttps://depositonce.tu-berlin.de//handle/11303/8492
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-7638
dc.language.isode
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.othermacrocyclic thioethersen
dc.subject.other1,4,7-trithiacyclononaneen
dc.subject.othercadmium iodide complexen
dc.subject.othermercuric iodide complexen
dc.titleMetallkomplexe mit 1,4,7-Trithiacyclononan: Kristallstrukturen von [CdI2 · C6H12S3]2 und [Hg(C6H12S3)2](HgI3)2de
dc.title.translatedMetal Complexes with 1,4,7-Trithiacyclononane: Crystal Structures of [CdI2 · C6H12S3]2 and [Hg(C6H12S3)2](HgI3)2en
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1515/znb-1993-0720
dcterms.bibliographicCitation.issue7
dcterms.bibliographicCitation.journaltitleZeitschrift für Naturforschung Bde
dcterms.bibliographicCitation.originalpublishernameDe Gruyteren
dcterms.bibliographicCitation.originalpublisherplaceBerlinen
dcterms.bibliographicCitation.pageend972
dcterms.bibliographicCitation.pagestart969
dcterms.bibliographicCitation.volume48
tub.accessrights.dnbfree
tub.affiliationFak. 2 Mathematik und Naturwissenschaften>Inst. Chemiede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinde
Files
Original bundle
Now showing 1 - 1 of 1
Loading…
Thumbnail Image
Name:
pickardt_shen_1993.pdf
Size:
3.56 MB
Format:
Adobe Portable Document Format
Description:
Collections