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Synthese und Eigenschaften von TrimethyIstannylmethyl-Indium(III)-Verbindungen

Schumann, Herbert; Mohtachemi, Reza

FG Anorganische Chemie - Festkörper- und Materialchemie

Trimethyltin methyllithium reacts with InCl3, CH3InCl2 and R2InCl (R = CH3, t-C4H9) with formation of the new compounds In(CH2SnMe3)3, CH3In(CH2SnMe3)2, (CH3)2InCH2SnMe3 and (t-C4H9)2InCH2SnMe3. The compounds are characterized by elemental analyses, 1H, 13C, 119Sn NMR and IR spectra.