Reductive cleavage of P-4 by iron(I) centres: synthesis and structural characterisation of Fe-2(P-2)(2) complexes with two bridging P-2(2-) ligands

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dc.contributor.authorYao, Shenglai
dc.contributor.authorSzilvási, Tibor
dc.contributor.authorLindenmaier, Nils
dc.contributor.authorXiong, Yun
dc.contributor.authorInoue, Shigeyoshi
dc.contributor.authorAdelhardt, Mario
dc.contributor.authorSutter, Jörg
dc.contributor.authorMeyer, Karsten
dc.contributor.authorDrieß, Matthias
dc.date.accessioned2017-10-25T06:27:48Z
dc.date.available2017-10-25T06:27:48Z
dc.date.issued2015
dc.description.abstractThe selective transformation of white phosphorus with a beta-diketiminato iron(I) toluene complex under mild reaction conditions is reported which furnishes a new dinuclear iron(III) Fe-2(P-2)(2) complex with two bridging P-2(2-) ligands. Its reduction with potassium results in the formation of the first delocalised mixed-valent bis-diphosphido iron(II,III) complex which is isostructural with the neutral Fe2P4 precursor.en
dc.identifier.eissn1364-548X
dc.identifier.issn1359-7345
dc.identifier.pmid25747898
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/6966
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-6305
dc.language.isoen
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.titleReductive cleavage of P-4 by iron(I) centres: synthesis and structural characterisation of Fe-2(P-2)(2) complexes with two bridging P-2(2-) ligandsen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/c5cc00147a
dcterms.bibliographicCitation.issue28
dcterms.bibliographicCitation.journaltitleChemical communicationsen
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistryde
dcterms.bibliographicCitation.originalpublisherplaceCambridgede
dcterms.bibliographicCitation.pageend6156
dcterms.bibliographicCitation.pagestart6153
dcterms.bibliographicCitation.volume51
tub.accessrights.dnbfree
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Metallorganische Chemie und Anorganische Materialiende
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Metallorganische Chemie und Anorganische Materialiende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlin

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