Synthesis of Silylated Cyclobutanone and Cyclobutene Derivatives Involving 1,4‐Addition of Zinc‐Based Silicon Nucleophiles
| dc.contributor.author | Cui, Ming | |
| dc.contributor.author | Oestreich, Martin | |
| dc.date.accessioned | 2022-04-01T07:40:36Z | |
| dc.date.available | 2022-04-01T07:40:36Z | |
| dc.date.issued | 2021-10-07 | |
| dc.date.updated | 2022-03-21T13:48:08Z | |
| dc.description.abstract | A copper‐catalyzed conjugate silylation of various cyclobutenone derivatives with Me2PhSiZnCl ⋅ 2LiCl or (Me2PhSi)2Zn ⋅ xLiCl (x≤4) to generate β‐silylated cyclobutanones is reported. Trapping the intermediate enolate with ClP(O)(OPh)2 affords silylated enol phosphates that can be further engaged in Kumada cross‐coupling reactions to yield silylated cyclobutene derivatives. | en |
| dc.description.sponsorship | TU Berlin, Open-Access-Mittel – 2021 | |
| dc.identifier.eissn | 1521-3765 | |
| dc.identifier.issn | 0947-6539 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/16642 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-15419 | |
| dc.language.iso | en | en |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | en |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.subject.other | conjugate addition | en |
| dc.subject.other | copper | en |
| dc.subject.other | silicon | en |
| dc.subject.other | synthetic methods | en |
| dc.subject.other | zinc | en |
| dc.title | Synthesis of Silylated Cyclobutanone and Cyclobutene Derivatives Involving 1,4‐Addition of Zinc‐Based Silicon Nucleophiles | en |
| dc.type | Article | en |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1002/chem.202102993 | en |
| dcterms.bibliographicCitation.issue | 65 | en |
| dcterms.bibliographicCitation.journaltitle | Chemistry – A European Journal | en |
| dcterms.bibliographicCitation.originalpublishername | Wiley | en |
| dcterms.bibliographicCitation.originalpublisherplace | New York, NY | en |
| dcterms.bibliographicCitation.pageend | 16106 | en |
| dcterms.bibliographicCitation.pagestart | 16103 | en |
| dcterms.bibliographicCitation.volume | 27 | en |
| tub.accessrights.dnb | free | en |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Organische Chemie / Synthese und Katalyse | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.group | FG Organische Chemie / Synthese und Katalyse | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin | en |