Density and partial molar volumes of the liquid mixture water + methanol + ethanol + 2-propanol at 298.15 K and 0.1 MPa

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dc.contributor.authorGuevara-Carrion, Gabriela
dc.contributor.authorFingerhut, Robin
dc.contributor.authorVrabec, Jadran
dc.date.accessioned2021-07-20T14:09:32Z
dc.date.available2021-07-20T14:09:32Z
dc.date.issued2021-06-01
dc.description.abstractThe density of the quaternary mixture water + methanol + ethanol + propan-2-ol and its four ternary and six binary subsystems is measured over a wide composition range at ambient temperature and pressure, that is, 298.15 K and 0.1 MPa. The resulting molar volume data are correlated with a response surface model, consisting of linear, quadratic, bilinear, and trilinear interaction terms. The density values obtained with this correlation are compared to molecular simulation results and experimental literature data. Further, the excess molar volume and the partial molar volumes are determined for the ternary and quaternary mixtures. The analytical solution for the partial molar volumes of a quaternary mixture for the response surface model is also given.en
dc.identifier.eissn1520-5134
dc.identifier.issn0021-9568
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/13429
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-12215
dc.language.isoenen
dc.relation.ispartof10.14279/depositonce-17521
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.ddc660 Chemische Verfahrenstechnikde
dc.subject.otherdensityen
dc.subject.otherpartial molar volumeen
dc.subject.otherwateren
dc.subject.otheralcoholen
dc.titleDensity and partial molar volumes of the liquid mixture water + methanol + ethanol + 2-propanol at 298.15 K and 0.1 MPaen
dc.typeArticleen
dc.type.versionacceptedVersionen
dcterms.bibliographicCitation.doi10.1021/acs.jced.1c00070en
dcterms.bibliographicCitation.issue6en
dcterms.bibliographicCitation.journaltitleJournal of chemical & engineering dataen
dcterms.bibliographicCitation.originalpublishernameAmerican Chemical Society (ACS)en
dcterms.bibliographicCitation.originalpublisherplaceColumbus, Ohioen
dcterms.bibliographicCitation.pageend2435en
dcterms.bibliographicCitation.pagestart2425en
dcterms.bibliographicCitation.volume66en
tub.accessrights.dnbdomain*
tub.affiliationFak. 3 Prozesswissenschaften::Inst. Prozess- und Verfahrenstechnik::FG Thermodynamik und Thermische Verfahrenstechnikde
tub.affiliation.facultyFak. 3 Prozesswissenschaftende
tub.affiliation.groupFG Thermodynamik und Thermische Verfahrenstechnikde
tub.affiliation.instituteInst. Prozess- und Verfahrenstechnikde
tub.publisher.universityorinstitutionTechnische Universität Berlinen

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