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🆕 Date Issued:
2016
🗄 In DepositOnce:2017-10-24
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Characterization of the [3Fe-4S](0/1+) cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses

Lauterbach, Lars; Gee, Leland B.; Pelmenschikov, Vladimir; Jenney, Francis E., Jr.; Kamali, Saeed; Yoda, Yoshitaka; Adams, Michael W. W.; Cramer, Stephen P.

The D14C variant of Pyrococcus furiosus ferredoxin provides an extraordinary framework to investigate a [3Fe-4S] cluster at two oxidation levels and compare the results to its physiologic [4Fe-4S] counterpart in the very same protein. Our spectroscopic and computational study reveals vibrational property changes related to the electronic and structural aspects of both Fe-S clusters.
Published in: Dalton transactions, 10.1039/c5dt04760a, Royal Society of Chemistry
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  • This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
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