X-Ray Structural Analysis and Vibrational Spectra of Sodium Cysteine-S-sulfonate, +H3NCH(COO-)CH2S2O3Na • 3/2H2O [1]

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dc.contributor.authorSteudel, Ralf
dc.contributor.authorAlbertsen, Angela
dc.contributor.authorKustos, Monika
dc.contributor.authorPickardt, Joachim
dc.date.accessioned2018-11-10T16:38:28Z
dc.date.available2018-11-10T16:38:28Z
dc.date.issued1993
dc.description.abstractThe title compound crystallizes orthorhombically (space group C 2221) with a = 797.0, b = 870.3 and c = 2739.0 pm. The anions are zwitterions which are heavily involved in intra- and intermolecular NH •••O and OH•••O hydrogen bonding. The two types of sodium cations are coordinated by six oxygen atoms each of which belongs to either SO3 groups (Na 2) or water molecules and SO3 groups (Na1). A second type of water molecules is not coordinated to the cations. The SS bond length is 208.2 pm. Infrared and Raman spectra of the title compound are reported and tentatively assigned. The SS stretching vibration is observed at 409 cm-1.en
dc.identifier.eissn1865-7117
dc.identifier.issn0932-0776
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/8494
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-7640
dc.language.isoen
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.othercysteineen
dc.subject.otherS-Sulfonateen
dc.subject.otherstructureen
dc.subject.otherspectraen
dc.subject.otherhydrogen bondsen
dc.titleX-Ray Structural Analysis and Vibrational Spectra of Sodium Cysteine-S-sulfonate, +H3NCH(COO-)CH2S2O3Na • 3/2H2O [1]en
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1515/znb-1993-0503
dcterms.bibliographicCitation.issue5
dcterms.bibliographicCitation.journaltitleZeitschrift für Naturforschung Bde
dcterms.bibliographicCitation.originalpublishernameDe Gruyteren
dcterms.bibliographicCitation.originalpublisherplaceBerlinen
dcterms.bibliographicCitation.pageend560
dcterms.bibliographicCitation.pagestart555
dcterms.bibliographicCitation.volume48
tub.accessrights.dnbfree
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemiede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinde
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