A Nanotubular Metal–Organic Framework with a Narrow Bandgap from Extended Conjugation**

dc.contributor.authorAyhan, M. Menaf
dc.contributor.authorBayraktar, Ceyda
dc.contributor.authorYu, Kai Bin
dc.contributor.authorHanna, Gabriel
dc.contributor.authorYazaydin, A. Ozgur
dc.contributor.authorZorlu, Yunus
dc.contributor.authorYücesan, Gündoğ
dc.date.accessioned2021-05-17T12:01:21Z
dc.date.available2021-05-17T12:01:21Z
dc.date.issued2020-10-15
dc.date.updated2020-12-07T13:41:33Z
dc.description.abstractA one‐dimensional nanotubular metal–organic framework (MOF) [Ni(Cu‐H4TPPA)]⋅2 (CH3)2NH2+ (H8TPPA=5,10,15,20‐tetrakis[p‐phenylphosphonic acid] porphyrin) constructed by using the arylphosphonic acid H8TPPA is reported. The structure of this MOF, known as GTUB‐4, was solved by using single‐crystal X‐ray diffraction and its geometric accessible surface area was calculated to be 1102 m2 g−1, making it the phosphonate MOF with the highest reported surface area. Due to the extended conjugation of its porphyrin core, GTUB‐4 possesses narrow indirect and direct bandgaps (1.9 eV and 2.16 eV, respectively) in the semiconductor regime. Thermogravimetric analysis suggests that GTUB‐4 is thermally stable up to 400 °C. Owing to its high surface area, low bandgap, and high thermal stability, GTUB‐4 could find applications as electrodes in supercapacitors.en
dc.identifier.eissn1521-3765
dc.identifier.issn0947-6539
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/13104
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-11897
dc.language.isoenen
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subject.ddc660 Chemische Verfahrenstechnikde
dc.subject.otherhigh surface areaen
dc.subject.otherligand designen
dc.subject.othermetal–organic frameworksen
dc.subject.othernanotubesen
dc.subject.othersemiconductive MOFsen
dc.titleA Nanotubular Metal–Organic Framework with a Narrow Bandgap from Extended Conjugation**en
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1002/chem.202001917en
dcterms.bibliographicCitation.issue65en
dcterms.bibliographicCitation.journaltitleChemistry – A European Journalen
dcterms.bibliographicCitation.originalpublishernameWileyen
dcterms.bibliographicCitation.originalpublisherplaceNew York, NYen
dcterms.bibliographicCitation.pageend14816en
dcterms.bibliographicCitation.pagestart14813en
dcterms.bibliographicCitation.volume26en
tub.accessrights.dnbfreeen
tub.affiliationFak. 3 Prozesswissenschaften>Inst. Lebensmitteltechnologie und Lebensmittelchemie>FG Lebensmittelchemie und Toxikologiede
tub.affiliation.facultyFak. 3 Prozesswissenschaftende
tub.affiliation.groupFG Lebensmittelchemie und Toxikologiede
tub.affiliation.instituteInst. Lebensmitteltechnologie und Lebensmittelchemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinen
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