One-step procedure for the preparation of functional polysaccharide/fatty acid multilayered coatings

dc.contributor.authorMicciulla, Samantha
dc.contributor.authorHayward, Dominic W.
dc.contributor.authorGerelli, Yuri
dc.contributor.authorPanzarella, Alain
dc.contributor.authorvon Klitzing, Regine
dc.contributor.authorGradzielski, Michael
dc.contributor.authorChiappisi, Leonardo
dc.date.accessioned2020-05-27T09:54:52Z
dc.date.available2020-05-27T09:54:52Z
dc.date.issued2019-06-04
dc.description.abstractSoft, stratified, amphiphilic systems are recurrent motifs in nature, e.g., in myelin sheaths or thylakoid stacks, and synthetic analogues are increasingly being exploited in the areas of biocatalysis, biosensing, and drug delivery. The synthesis of such complex multilayered systems usually requires lengthy preparation protocols. Here, we demonstrate the formation of multilayered fatty acid/polysaccharide thin films prepared via a single step protocol, which exploits the spontaneous self-assembly of the components into vesicular systems in aqueous solution. The solutions are characterized by light and neutron scattering experiments and the thin films by neutron reflectometry, optical ellipsometry, atomic force microscopy, and x-ray diffraction. The thin films exhibit structural features with sub-10 nm dimensions, stemming from the ordered sequence of hydrophilic and hydrophobic layers and respond strongly to changes in ambient humidity. Using this approach, films with a total thickness varying from tens to hundreds of nanometers can be easily prepared.en
dc.description.sponsorshipBMBF, 05K16KT1, SANS an funktionalen Soft-Matter Proben während des Herstellungsprozesses und in komplexen Umgebungenen
dc.description.sponsorshipEC/H2020/731096/EU/The Future of ILL 2030/FILL2030en
dc.identifier.eissn2399-3669
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/11229
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-10117
dc.language.isoen
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.otherthin filmsen
dc.subject.othersynthesisen
dc.subject.otheraqueous solutionsen
dc.subject.otherself-assemblyen
dc.titleOne-step procedure for the preparation of functional polysaccharide/fatty acid multilayered coatingsen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.articlenumber61
dcterms.bibliographicCitation.doi10.1038/s42004-019-0155-y
dcterms.bibliographicCitation.issue1
dcterms.bibliographicCitation.journaltitleCommunications Chemistryen
dcterms.bibliographicCitation.originalpublishernameSpringer Natureen
dcterms.bibliographicCitation.originalpublisherplaceLondon [u.a.]en
dcterms.bibliographicCitation.volume2
tub.accessrights.dnbfree
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Physikalische Chemie / Molekulare Materialwissenschaftende
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Physikalische Chemie / Molekulare Materialwissenschaftende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinde

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