An EMF cell with a nitrogen solid electrolyte-on the transference of nitrogen ions in yttria-stabilized zirconia

Simple item page
dc.contributor.authorLee, Doh-Kwon
dc.contributor.authorFischer, Claus C.
dc.contributor.authorValov, Ilia
dc.contributor.authorReinacher, Jochen
dc.contributor.authorStork, Alexandra
dc.contributor.authorLerch, Martin
dc.contributor.authorJanek, Jürgen
dc.date.accessioned2016-07-01T06:27:30Z
dc.date.available2016-07-01T06:27:30Z
dc.date.issued2011
dc.descriptionDieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.de
dc.descriptionThis publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.en
dc.description.abstractThe mobility and electrochemical activity of nitrogen inside and/or at the surface of ionic compounds is of fundamental, as well as of possibly practical, relevance. In order to better understand the role of nitrogen anions in solid electrolytes, we measured the transference number of nitrogen in yttria-stabilized zirconia (YSZ) by a concentration cell technique as a function of oxygen activity at different temperatures in the range of 1023 ≤ T/K ≤ 1123. YSZ doped with 1.9 wt% of N (YSZ:N) turned out to have an appreciable nitrogen transference number, which increased from 0 to 0.1 with decreasing oxygen activity in the range of −20 < logaO2 < −14. The stability of N in YSZ:N, however, has yet to be elucidated under oxidizing conditions.en
dc.description.sponsorshipDFG, SPP 1136, Substitutionseffekte in ionischen Festkörpernen
dc.identifier.eissn1463-9084
dc.identifier.issn1463-9076
dc.identifier.pmid21079879
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/5744
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-5364
dc.language.isoen
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.titleAn EMF cell with a nitrogen solid electrolyte-on the transference of nitrogen ions in yttria-stabilized zirconiaen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/c003991h
dcterms.bibliographicCitation.issue3
dcterms.bibliographicCitation.journaltitlePhysical chemistry, chemical physicsen
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistryde
dcterms.bibliographicCitation.originalpublisherplaceCambridgede
dcterms.bibliographicCitation.pageend1242
dcterms.bibliographicCitation.pagestart1239
dcterms.bibliographicCitation.volume13
tub.accessrights.dnbdomain
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemiede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlin

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
c003991h.pdf
Size:
1.3 MB
Format:
Adobe Portable Document Format
Download

Collections

Publications