Anchoring an Iridium Pincer Complex in a Hydrophobic Microporous Polymer for Application in Continuous‐Flow Alkane Dehydrogenation
| dc.contributor.author | König, Michaela | |
| dc.contributor.author | Traxler, Michael | |
| dc.contributor.author | Rudolph, Maik Alexander | |
| dc.contributor.author | Schmidt, Johannes | |
| dc.contributor.author | Küçükkeçeci, Hüseyin | |
| dc.contributor.author | Schomäcker, Reinhard | |
| dc.contributor.author | Thomas, Arne | |
| dc.date.accessioned | 2022-12-15T12:51:02Z | |
| dc.date.available | 2022-12-15T12:51:02Z | |
| dc.date.issued | 2022-08-18 | |
| dc.date.updated | 2022-11-22T16:56:31Z | |
| dc.description.abstract | An iridium pincer complex {p‐KO‐C6H2‐2,6‐[OP(t‐Bu)2]2}Ir(C2H4) is immobilized in a propyl bromide‐functionalized microporous polymer network using the concepts of surface organometallic chemistry. The support material enables the formation of isolated active metal sites embedded in a chemically robust and highly hydrophobic environment. The catalyst maintained high porosity and – without prior activation – exhibited high activity in the continuous‐flow dehydrogenation of cyclohexane at elevated temperatures. The catalyst shows a stable performance for at least 7 days, even when additional H2O was co‐fed, owing to its hydrophobic nature. | en |
| dc.description.sponsorship | DFG, 390540038, EXC 2008: Unifying Systems in Catalysis "UniSysCat" | |
| dc.description.sponsorship | TU Berlin, Open-Access-Mittel – 2022 | |
| dc.identifier.eissn | 1867-3899 | |
| dc.identifier.issn | 1867-3880 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/17818 | |
| dc.identifier.uri | https://doi.org/10.14279/depositonce-16607 | |
| dc.language.iso | en | |
| dc.relation.ispartof | 10.14279/depositonce-16653 | |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.subject.other | catalysis | |
| dc.subject.other | dehydrogenation | |
| dc.subject.other | microporous polymer network | |
| dc.subject.other | pincer | |
| dc.title | Anchoring an Iridium Pincer Complex in a Hydrophobic Microporous Polymer for Application in Continuous‐Flow Alkane Dehydrogenation | en |
| dc.type | Article | |
| dc.type.version | publishedVersion | |
| dcterms.bibliographicCitation.articlenumber | e202200811 | |
| dcterms.bibliographicCitation.doi | 10.1002/cctc.202200811 | |
| dcterms.bibliographicCitation.issue | 18 | |
| dcterms.bibliographicCitation.journaltitle | ChemCatChem | en |
| dcterms.bibliographicCitation.originalpublishername | Wiley | |
| dcterms.bibliographicCitation.originalpublisherplace | New York, NY | |
| dcterms.bibliographicCitation.volume | 14 | |
| tub.accessrights.dnb | free | |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Funktionsmaterialien | |
| tub.publisher.universityorinstitution | Technische Universität Berlin |