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The preparation, characterisation and electronic structures of 2,4-pentadiynylnitrile (cyanobutadiynyl) complexes
Bock, Sören; Eaves, Samantha G.; Parthey, Matthias; Kaupp, Martin; Guennic, Boris le; Halet, Jean-François; Yufit, Dmitry S.; Howard, Judith A. K.; Low, Paul J.
Convenient preparative routes to mononuclear ruthenium complexes containing the 2,4-pentadiynylnitrile, or cyanobutadiynyl, ligand are described. The electronic properties of the [C5N]− ligand are closely related to those of not only the cyanide ([CN]−) and 2-propynylnitrile or cyanoacetylide ([C[triple bond, length as m-dash]CC[triple bond, length as m-dash]N]−) ligands, but also those of the isoelectronic polyynyl ([{C[triple bond, length as m-dash]C}nR]−) ligands.
Published in: Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry, 10.1039/c3dt33052d, Royal Society of Chemistry
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- This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
