Kristallstruktur des „supramolekularen“ Silber(I)thiocyanat-Cyclam-Komplexes [Ag(SCN)·(C10H24N4)1/2]

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dc.contributor.authorPickardt, Joachim
dc.contributor.authorShen, Jing
dc.date.accessioned2018-11-10T16:38:15Z
dc.date.available2018-11-10T16:38:15Z
dc.date.issued1994
dc.description.abstractColourless crystals of the 1,4,8,11-tetraazacyclotetradecane (cyclam) silver(I) thiocyanate complex [Ag(SCN) · (C10H24N4)1/2] were obtained by diffusion of a solution of cyclam in ethanol into an aqueous solution of K[Ag(SCN)2], The crystals are tetragonal, space group P42/n, Z = 8, a = b - 1256.0(4), c = 1185.5(9) pm. The SCN groups act as μ3 ligands, the S atoms of two SCN groups bridge two neighbouring Ag ions, which are only 297.5 pm apart, forming butterfly-like Ag2S2 moieties, the N atoms of the SCN groups form bonds to Ag atoms of adjacent Ag2S2 moieties. Two Ag2S2 units are again connected by cyclam molecules which act as two-dentate bridging ligands. Thus a complicated three-dimensional “supramolecular” structure results.en
dc.identifier.eissn1865-7117
dc.identifier.issn0932-0776
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/8491
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-7637
dc.language.isode
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.other1,4,8,11-Tetraazacyclotetradecaneen
dc.subject.otherSilver(I) Thiocyanate complexen
dc.subject.othercrystal structureen
dc.titleKristallstruktur des „supramolekularen“ Silber(I)thiocyanat-Cyclam-Komplexes [Ag(SCN)·(C10H24N4)1/2]de
dc.title.translatedCrystal Structure of the “Supramolecular” Silver(I)thiocyanate Cyclam Complex [Ag(SCN)·(C10H24N4)1/2]en
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1515/znb-1994-0209
dcterms.bibliographicCitation.issue2
dcterms.bibliographicCitation.journaltitleZeitschrift für Naturforschung Bde
dcterms.bibliographicCitation.originalpublishernameDe Gruyteren
dcterms.bibliographicCitation.originalpublisherplaceBerlinen
dcterms.bibliographicCitation.pageend214
dcterms.bibliographicCitation.pagestart211
dcterms.bibliographicCitation.volume49
tub.accessrights.dnbfree
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemiede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlinde

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