Isolation of the Phytochrome Chromophore. The Cleavage Reaction with Hydrogen Bromide
dc.contributor.author | Rüdiger, Wolfhart | |
dc.contributor.author | Brandlmeier, Thomas | |
dc.contributor.author | Blos, Inge | |
dc.contributor.author | Gossauer, Albert | |
dc.contributor.author | Weller, Jens-Peter | |
dc.date.accessioned | 2019-01-04T13:17:57Z | |
dc.date.available | 2019-01-04T13:17:57Z | |
dc.date.issued | 1980 | |
dc.description.abstract | The cleavage of the bilin chromophore from C-phycocyanin with hydrogen bromide yields 3E-configurated phycocyanobilin (4) as the major and 3 Z-configurated phycocyanobilin (5) as the minor reaction product. The reaction of synthetic 3E-configurated phytochromobilin (2) with hydrogen bromide and methanol leads only to a methanol adduct at the C-18 side chain (7) whereas the same reaction with the 3Z-configurated phytochromobilin (3) leads to 7 and 2. The bilin chromophore was cleaved also from phytochrome after preparation of phytochromobilin peptides. The detection of 2 and 7 suggested that 3Z-and 3E-configurated phytochromobilin were the primary products of cleavage from phytochrome. A reaction scheme is given which can explain the results of the reaction with hydrogen bromide and methanol. | en |
dc.identifier.eissn | 1865-7125 | |
dc.identifier.issn | 0939-5075 | |
dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/8810 | |
dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-7939 | |
dc.language.iso | en | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject.ddc | 570 Biowissenschaften; Biologie | de |
dc.subject.other | phytochrome | en |
dc.subject.other | bile pigments | en |
dc.subject.other | phytochromobilin | en |
dc.subject.other | thioether cleavage | en |
dc.subject.other | c-phycocyanin | en |
dc.title | Isolation of the Phytochrome Chromophore. The Cleavage Reaction with Hydrogen Bromide | en |
dc.type | Article | en |
dc.type.version | publishedVersion | en |
dcterms.bibliographicCitation.doi | 10.1515/znc-1980-9-1018 | |
dcterms.bibliographicCitation.issue | 9-10 | |
dcterms.bibliographicCitation.journaltitle | Zeitschrift für Naturforschung C | de |
dcterms.bibliographicCitation.originalpublishername | De Gruyter | en |
dcterms.bibliographicCitation.originalpublisherplace | Berlin | |
dcterms.bibliographicCitation.pageend | 769 | |
dcterms.bibliographicCitation.pagestart | 763 | |
dcterms.bibliographicCitation.volume | 35 | |
tub.accessrights.dnb | free | |
tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Organische Chemie | de |
tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
tub.affiliation.group | FG Organische Chemie | de |
tub.affiliation.institute | Inst. Chemie | de |
tub.publisher.universityorinstitution | Technische Universität Berlin | de |
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