Vapor–Liquid Equilibria of Nitrogen + Diethyl Ether and Nitrogen + 1,1,1,2,2,4,5,5,5-Nonafluoro-4-(trifluoromethyl)-3-pentanone by Experiment, Peng–Robinson and PC-SAFT Equations of State

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dc.contributor.authorLinnemann, Matthias
dc.contributor.authorVrabec, Jadran
dc.date.accessioned2020-04-27T07:50:27Z
dc.date.available2020-04-27T07:50:27Z
dc.date.issued2017-06-01
dc.description.abstractThe saturated liquid line of the systems nitrogen (N2) + diethyl ether and N2 + 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone (Novec 649) is measured along three isotherms, that is, 390, 420, and 450 K and 360, 390, and 420 K, respectively. The employed gas solubility apparatus, based on the synthetic method, allows to measure points up to the critical region of these mixtures. The experimental data are used to correlate the Peng–Robinson and PC-SAFT equations of state (EOS). For the parametrization of the system, N2 + diethyl ether the Peng–Robinson EOS is combined with the Huron–Vidal mixing rule and the non-random two-liquid (NRTL) excess Gibbs energy model; for the system N2 + Novec 649 the quadratic mixing rule is used.en
dc.identifier.eissn1520-5134
dc.identifier.issn0021-9568
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/11014
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-9906
dc.language.isoenen
dc.relation.ispartof10.14279/depositonce-9842
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.ddc660 Chemische Verfahrenstechnikde
dc.subject.otherliquidsen
dc.subject.othertheoretical chemistryen
dc.subject.othercomputational chemistryen
dc.subject.otherethersen
dc.subject.othernitrogen ethyl groupsen
dc.subject.othersolubilityen
dc.titleVapor–Liquid Equilibria of Nitrogen + Diethyl Ether and Nitrogen + 1,1,1,2,2,4,5,5,5-Nonafluoro-4-(trifluoromethyl)-3-pentanone by Experiment, Peng–Robinson and PC-SAFT Equations of Stateen
dc.typeArticleen
dc.type.versionacceptedVersionen
dcterms.bibliographicCitation.doi10.1021/acs.jced.7b00217en
dcterms.bibliographicCitation.issue7en
dcterms.bibliographicCitation.journaltitleJournal of Chemical and Engineering Dataen
dcterms.bibliographicCitation.originalpublishernameAmerican Chemical Society (ACS)en
dcterms.bibliographicCitation.originalpublisherplaceColumbus, Ohioen
dcterms.bibliographicCitation.pageend2114en
dcterms.bibliographicCitation.pagestart2110en
dcterms.bibliographicCitation.volume62en
tub.accessrights.dnbfreeen
tub.affiliationFak. 3 Prozesswissenschaften::Inst. Prozess- und Verfahrenstechnik::FG Thermodynamik und Thermische Verfahrenstechnikde
tub.affiliation.facultyFak. 3 Prozesswissenschaftende
tub.affiliation.groupFG Thermodynamik und Thermische Verfahrenstechnikde
tub.affiliation.instituteInst. Prozess- und Verfahrenstechnikde
tub.publisher.universityorinstitutionTechnische Universität Berlinen

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