Phosphinosilylenes as a novel ligand system for heterobimetallic complexes

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dc.contributor.authorBreit, Nora C.
dc.contributor.authorEisenhut, Carsten
dc.contributor.authorInoue, Shigeyoshi
dc.date.accessioned2017-10-24T07:15:41Z
dc.date.available2017-10-24T07:15:41Z
dc.date.issued2016
dc.description.abstractA dihydrophosphinosilylene iron complex [LSi{Fe(CO)(4)}PH2] has been prepared and utilized in the synthesis of novel heterobimetallic complexes. The phosphine moiety in this phosphinosilylene complex allows coordination towards tungsten leading to the iron-tungsten heterobimetallic complex [LSi{Fe(CO)(4)}PH2{W(CO)(5)}]. In contrast, the reaction of [LSi{Fe(CO)(4)}PH2] with ethylenebis(triphenylphosphine)platinum(0) results in the formation of the iron-platinum heterobimetallic complex [LSi{Fe(CO)(4)}PH{PtH(PPh3)(2)}] via oxidative addition.en
dc.identifier.eissn1364-548X
dc.identifier.issn1359-7345
dc.identifier.pmid26974121
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/6907
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-6246
dc.language.isoen
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.titlePhosphinosilylenes as a novel ligand system for heterobimetallic complexesen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/c6cc00601a
dcterms.bibliographicCitation.issue32
dcterms.bibliographicCitation.journaltitleChemical communicationsen
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistryde
dcterms.bibliographicCitation.originalpublisherplaceCambridgede
dcterms.bibliographicCitation.pageend5526
dcterms.bibliographicCitation.pagestart5523
dcterms.bibliographicCitation.volume52
tub.accessrights.dnbfree
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Anorganische Chemie - Festkörper- und Materialchemiede
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Anorganische Chemie - Festkörper- und Materialchemiede
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlin

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