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Tunable absorption and emission wavelength in conjugated microporous polymers by copolymerization

Brandt, Jessica; Schmidt, Johannes; Thomas, Arne; Epping, Jan Dirk; Weber, Jens

Conjugated, microporous polymers based on a spirobifluorene core were synthesized by Suzuki polycondensation of the tetrabromospirobifluorene with benzene diboronic acid and/or thiophene diboronic acid. The optical properties (absorption and emission spectra) and the gas sorption properties (N2 and CO2) are analyzed and discussed.
Published in: Polymer chemistry, 10.1039/c1py00217a, Royal Society of Chemistry
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