Deca(4-methylbenzyl)ferrocen und -stannocen
| dc.contributor.author | Schumann, Herbert | |
| dc.contributor.author | Sühring, Klaudia | |
| dc.contributor.author | Weimann, Roman | |
| dc.contributor.author | Hummert, Markus | |
| dc.date.accessioned | 2018-10-15T11:11:22Z | |
| dc.date.available | 2018-10-15T11:11:22Z | |
| dc.date.issued | 2005 | |
| dc.description.abstract | Cyclopentadiene reacts with five equivalents of 4-methylbenzylalcohol (1:5,6 mole ratio) and sodium yielding penta(4-methylbenzyl)cyclopenta-2,4-diene (1), which upon treatment with butyl lithium affords the lithium salt [(4-MeC6H4CH2)5C5]Li (2). The reactions of 2 with FeCl2 and SnCl2 result in the formation of deca(4-methylbenzyl)ferrocene (3) and deca(4-methylbenzyl)stannocene (4), respectively. The 1H and 13C NMR, IR and mass spectra of the new compounds as well as the single crystal X-ray structure analysis of 1 are reported and discussed. | en |
| dc.identifier.eissn | 1865-7117 | |
| dc.identifier.issn | 0932-0776 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/8346 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-7498 | |
| dc.language.iso | de | |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.subject.other | Cyclopentadiene | en |
| dc.subject.other | Ferrocene | en |
| dc.subject.other | Stannocene | en |
| dc.title | Deca(4-methylbenzyl)ferrocen und -stannocen | de |
| dc.title.translated | Deca(4-methylbenzyl)ferrocene and -stannocene | en |
| dc.type | Article | en |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1515/znb-2005-0508 | |
| dcterms.bibliographicCitation.issue | 5 | |
| dcterms.bibliographicCitation.journaltitle | Zeitschrift für Naturforschung B | de |
| dcterms.bibliographicCitation.originalpublishername | De Gruyter | en |
| dcterms.bibliographicCitation.originalpublisherplace | Berlin | en |
| dcterms.bibliographicCitation.pageend | 532 | |
| dcterms.bibliographicCitation.pagestart | 527 | |
| dcterms.bibliographicCitation.volume | 60 | |
| tub.accessrights.dnb | free | |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin | de |
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