A straightforward zinc-catalysed reduction of sulfoxides to sulfides
| dc.contributor.author | Enthaler, Stephan | |
| dc.date.accessioned | 2016-06-30T06:33:36Z | |
| dc.date.available | 2016-06-30T06:33:36Z | |
| dc.date.issued | 2011 | |
| dc.description | Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich. | de |
| dc.description | This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively. | en |
| dc.description.abstract | In the present study, the zinc-catalysed reduction of a variety of sulfoxides with silanes as reductant to the corresponding sulfide has been examined in detail. With the straightforward and commercially available zinc(II) triflate as pre-catalyst, excellent yields and chemoselectivities were feasible. After studying the reaction conditions and the scope and limitations several attempts were undertaken to shed light on the reaction mechanism. | en |
| dc.description.sponsorship | DFG, EXC 314, Unifying Concepts in Catalysis | en |
| dc.identifier.eissn | 2044-4761 | |
| dc.identifier.issn | 2044-4753 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/5731 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-5351 | |
| dc.language.iso | en | |
| dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | en |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.title | A straightforward zinc-catalysed reduction of sulfoxides to sulfides | en |
| dc.type | Article | en |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1039/c0cy00039f | |
| dcterms.bibliographicCitation.issue | 1 | |
| dcterms.bibliographicCitation.journaltitle | Catalysis science & technology : a multidisciplinary journal focussing on all fundamental science and technological aspects of catalysis | en |
| dcterms.bibliographicCitation.originalpublishername | Royal Society of Chemistry | de |
| dcterms.bibliographicCitation.originalpublisherplace | Cambridge | de |
| dcterms.bibliographicCitation.pageend | 110 | |
| dcterms.bibliographicCitation.pagestart | 104 | |
| dcterms.bibliographicCitation.volume | 1 | |
| tub.accessrights.dnb | domain | |
| tub.affiliation | Verbundforschung::Exzellenzcluster (EXC)::EXC - UniCat | de |
| tub.affiliation.faculty | Verbundforschung | de |
| tub.affiliation.group | EXC - UniCat | de |
| tub.affiliation.institute | Exzellenzcluster (EXC) | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin |
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