Di-, Hexa- und Deca-substituierte Decaphenylferrocene
| dc.contributor.author | Schumann, Herbert | |
| dc.contributor.author | Sühring, Klaudia | |
| dc.date.accessioned | 2018-10-15T11:11:36Z | |
| dc.date.available | 2018-10-15T11:11:36Z | |
| dc.date.issued | 2005 | |
| dc.description.abstract | 5-Bromo-1,2,3,4-tetraphenyl-5-p-tolyl-1,3-cyclopentadiene (1a), 5-Bromo-1,4-di-phenyl-2,3,5- tri-p-tolyl-1,3-cyclopentadiene (1b), 5-Bromo-1,2,3,4,5-penta-p-tolyl-1,3-cyclopentadiene (1c), 5- Bromo-1,2,3,4-tetraphenyl-5-p-bromophenyl-1,3-cyclopentadiene (1d), and 5-Bromo-1,2,3,4-tetraphenyl- 5-p-anisyl-1,3-cyclopentadiene (1e) react with ironpentacarbonyl in m-xylene to yield the corresponding ferrocenes 2a - 2e. In the course of the purification procedure, reactions with HCl and the solvent m-xylene are observed which yield the mixed ionic sandwich complexes [(C5Ph4C6H4Me)Fe(C6H4Me2)]+Cl− (3a), [(C5Ph2(C6H4Me)3)Fe(C6H4Me2)]+Cl− (3b), [(C5(C6H4Me)5)Fe(C6H4Me2)]+Cl− (3c), [(C5Ph4C6H4Br)Fe(C6H4Me2)]+Cl− (3d), and [(C5Ph4 C6H4OMe)Fe(C6H4Me2)]+Cl− (3e), respectively, along with the corresponding cyclopentadienes 1,2,3,4-tetraphenyl-5-p-tolyl-1,3-cyclopentadiene (4a), 1,4-diphenyl-2,3,5-tri-p-tolyl-1,3- cyclopentadiene (4b), 1,2,3,4,5-penta-p-tolyl-1,3-cyclopentadiene (4c), 1,2,3,4-tetraphenyl-5-pbromphenyl- 1,3-cyclopentadiene (4d), and 1,2,3,4-tetraphenyl-5-p-anisyl-1,3-cyclopentadiene (4e). The compounds have been characterized by elemental analysis, IR, NMR, and mass spectra, and, in the case of 2c, by 13C-CPMAS spectroscopy and X-ray powder diffractometry. | en |
| dc.identifier.eissn | 1865-7117 | |
| dc.identifier.issn | 0932-0776 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/8349 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-7501 | |
| dc.language.iso | de | |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.subject.other | Cyclopentadiene | en |
| dc.subject.other | Ferrocene | en |
| dc.subject.other | Xylene complex | en |
| dc.subject.other | Tetraphenylferrocene derivatives | en |
| dc.subject.other | Octaphenylferrocene derivatives | en |
| dc.title | Di-, Hexa- und Deca-substituierte Decaphenylferrocene | de |
| dc.title.translated | Di-, Hexa- and Deca-Substituted Decaphenylferrocenes | en |
| dc.type | Article | en |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1515/znb-2005-0404 | |
| dcterms.bibliographicCitation.issue | 4 | |
| dcterms.bibliographicCitation.journaltitle | Zeitschrift für Naturforschung B | de |
| dcterms.bibliographicCitation.originalpublishername | De Gruyter | en |
| dcterms.bibliographicCitation.originalpublisherplace | Berlin | en |
| dcterms.bibliographicCitation.pageend | 388 | |
| dcterms.bibliographicCitation.pagestart | 383 | |
| dcterms.bibliographicCitation.volume | 60 | |
| tub.accessrights.dnb | free | |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin | de |
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