Carbamoyl Derivatives of a Pyridine-Based Tetraamine

Bilakhiya, Anvarhusen K.; Heinemann, Frank W.; Grohmann, Andreas

Carbamoyl Derivatives of a Pyridine-Based Tetraamine

dc.contributor.author	Bilakhiya, Anvarhusen K.
dc.contributor.author	Heinemann, Frank W.
dc.contributor.author	Grohmann, Andreas
dc.date.accessioned	2018-10-10T07:34:22Z
dc.date.available	2018-10-10T07:34:22Z
dc.date.issued	2007
dc.description.abstract	The reaction of four equivalents of phenyl or tert-butyl isocyanate with the pyridine-derived tetraamine 2,6-C3H3N[CMe(CH2NH2)2]2 in toluene gives high yields of the quadruply ureido substituted products 2,6-C5H3N[CMe(CH2R)2]2 [R = -NH(CO)NHPh and -NH(CO)NHtBu]. Full spectroscopic data for both compounds are given. A single crystal X-ray structure determination of the phenyl derivative reveals an intricate network of both intra- and intermolecular hydrogen bonds involving the C=O and both NH functionalities in all ureido groups.	en
dc.description.sponsorship	DFG, SPP 1118, Sekundäre Wechselwirkungen als Steuerungsprinzip zur gerichteten Funktionalisierung reaktionsträger Substrate	en
dc.identifier.eissn	1865-7117
dc.identifier.issn	0932-0776
dc.identifier.uri	https://depositonce.tu-berlin.de/handle/11303/8308
dc.identifier.uri	http://dx.doi.org/10.14279/depositonce-7459
dc.language.iso	en
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc	540 Chemie und zugeordnete Wissenschaften	de
dc.subject.other	Tetrapodal Pentadentate Ligand	en
dc.subject.other	Urea	en
dc.subject.other	Chelates	en
dc.subject.other	Hydrogen Bonding	en
dc.title	Carbamoyl Derivatives of a Pyridine-Based Tetraamine	en
dc.type	Article	en
dc.type.version	publishedVersion	en
dcterms.bibliographicCitation.doi	10.1515/znb-2007-0405
dcterms.bibliographicCitation.issue	4
dcterms.bibliographicCitation.journaltitle	Zeitschrift für Naturforschung B	de
dcterms.bibliographicCitation.originalpublishername	De Gruyter	en
dcterms.bibliographicCitation.originalpublisherplace	Berlin	en
dcterms.bibliographicCitation.pageend	522
dcterms.bibliographicCitation.pagestart	519
dcterms.bibliographicCitation.volume	62
tub.accessrights.dnb	free
tub.affiliation	Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie	de
tub.affiliation.faculty	Fak. 2 Mathematik und Naturwissenschaften	de
tub.affiliation.institute	Inst. Chemie	de
tub.publisher.universityorinstitution	Technische Universität Berlin	de

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