Formation of N-heterocyclic, donor-stabilized borenium ions

dc.contributor.authorSomeya, Chika I.
dc.contributor.authorInoue, Shigeyoshi
dc.contributor.authorPräsang, Carsten
dc.contributor.authorIrran, Elisabeth
dc.contributor.authorDrieß, Matthias
dc.date.accessioned2016-06-30T06:33:36Z
dc.date.available2016-06-30T06:33:36Z
dc.date.issued2011
dc.descriptionDieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.de
dc.descriptionThis publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.en
dc.description.abstractCationic and zwitterionic boryl bromide species and a borenium–boryl bromide cation have been synthesised which represent new N-donor stabilised cationic boron compounds with β-diketiminate ligands. The unexpected borenium–boryl bromide results from a head-to-tail dimerisation of the corresponding zwitterionic boryl bromide accompanied by proton migration. The electronic nature of these new species was studied by DFT calculations.en
dc.identifier.eissn1364-548X
dc.identifier.issn1359-7345
dc.identifier.pmid21519618
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/5733
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-5353
dc.language.isoen
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.titleFormation of N-heterocyclic, donor-stabilized borenium ionsen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/c1cc11789k
dcterms.bibliographicCitation.issue23
dcterms.bibliographicCitation.journaltitleChemical communicationsen
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistryde
dcterms.bibliographicCitation.originalpublisherplaceCambridgede
dcterms.bibliographicCitation.pageend6601
dcterms.bibliographicCitation.pagestart6599
dcterms.bibliographicCitation.volume47
tub.accessrights.dnbdomain
tub.affiliationFak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Metallorganische Chemie und Anorganische Materialiende
tub.affiliation.facultyFak. 2 Mathematik und Naturwissenschaftende
tub.affiliation.groupFG Metallorganische Chemie und Anorganische Materialiende
tub.affiliation.instituteInst. Chemiede
tub.publisher.universityorinstitutionTechnische Universität Berlin

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