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State of Health Assessment of Spent Lithium-Ion Batteries Based on Voltage Integral During the Constant Current Charge
Amuta, Ote; Kowal, Julia (Contributor)
Lithium-ion battery (LIB) is used in many personal electronic devices (PED) and energy-demanding applications such as electric vehicles. After their first use, rather than dispose of them for recycling, some may have reasonable capacity and can be used in a secondary application. The current test methods to assess them are either slow, complex or expensive. The voltage integral during the constant current (CC) charge of the same model LIBs strongly correlates with the state of health (SOH) and is faster than a full capacity check. As against the filtering requirement in the incremental capacity (IC), Differential Voltage (DV) or the complex analysis in the electrochemical impedance spectrum(EIS), the voltage integral offers simple integration, just like the simple capacity Coulomb’s counter that is installed in many BMS for estimating the SOC of LIBs. By obtaining the voltage integral of a relatively new cell and an old cell of the same model with known SOH at a given ambient temperature and CC charge, the SOH of other similar cells can be easily estimated by finding their voltage integral. This research was funded by the German Academic Exchange Service (DAAD) and 335 Petroleum Technology Development Fund (PTDF) under the Nigerian-German Postgraduate Training Programme PhD, 2022, grant number 57610608.