Die Kristallstrukturen von Strontium- und Bariumhexacyanoferrat(III)-Hexamethylentetramin-Hydraten. Strukturmodell für Additionsverbindungen der Alkali- und Erdalkalimetallhexacyanoferrate mit Hexamethylentetramin Strontium and Barium
dc.contributor.author | Meyer, Hans-Jürgen | |
dc.contributor.author | Pickardt, Joachim | |
dc.date.accessioned | 2019-01-02T09:33:40Z | |
dc.date.available | 2019-01-02T09:33:40Z | |
dc.date.issued | 1989 | |
dc.description.abstract | By reaction of methanolic solutions of hexamethylenetetramine with aqueous solutions of hexacyanoferrates(III) of strontium and barium resp., crystals of the compounds were obtained. Sr3[Fe(CN)6]2 · 3 C6H12N4 · 18 H2O, tetragonal, space group P42/nmc, Z = 4, a = 1931.8(4), c = 1579.9(4) pm, 1358 reflections. R = 0.066. Ba3[Fe(CN)6]2 · 2 C6H12N4 · 11 Η2Ο. monoclinic. space group P21/n, Ζ = 2, a = 1148.0(4), b = 1369.7(4), c = 1584.5(4) pm, γ = 95.79(3)°, 2583 reflections, R = 0.057. The crystal structures of these adducts are compared with those of other hexamethylenetetramine adducts of alkaline and alkaline earth metal hexacyanoferrates of the general formula M,[Fe(CN)6]y · zC6H12N4 · vH2O recently investigated by us. A structural model for the adducts is presented | en |
dc.identifier.eissn | 1865-7117 | |
dc.identifier.issn | 0932-0776 | |
dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/8750 | |
dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-7879 | |
dc.language.iso | de | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
dc.subject.other | Kristallstruktur | de |
dc.subject.other | Hexamethylentetramin | de |
dc.title | Die Kristallstrukturen von Strontium- und Bariumhexacyanoferrat(III)-Hexamethylentetramin-Hydraten. Strukturmodell für Additionsverbindungen der Alkali- und Erdalkalimetallhexacyanoferrate mit Hexamethylentetramin Strontium and Barium | de |
dc.title.translated | The Crystal Structures of Hydrates of Strontium and Barium Hexacyanoferrate(III) with Hexamethylenetetramine. Structural Model for Adducts of the Hexacyanoferrates of Alkaline and Alkaline Earth Metals with Hexamethylenetetramine | en |
dc.type | Article | en |
dc.type.version | publishedVersion | en |
dcterms.bibliographicCitation.doi | 10.1515/znb-1989-0503 | |
dcterms.bibliographicCitation.issue | 5 | |
dcterms.bibliographicCitation.journaltitle | Zeitschrift für Naturforschung B | de |
dcterms.bibliographicCitation.originalpublishername | De Gruyter | en |
dcterms.bibliographicCitation.originalpublisherplace | Berlin | |
dcterms.bibliographicCitation.pageend | 525 | |
dcterms.bibliographicCitation.pagestart | 519 | |
dcterms.bibliographicCitation.volume | 44 | |
tub.accessrights.dnb | free | |
tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Anorganische Chemie - Festkörper- und Materialchemie | de |
tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
tub.affiliation.group | FG Anorganische Chemie - Festkörper- und Materialchemie | de |
tub.affiliation.institute | Inst. Chemie | de |
tub.publisher.universityorinstitution | Technische Universität Berlin | de |
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